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Heterogeneous Catalysis of Mixed Oxides [electronic resource] : Perovskite and Heteropoly Catalysts / edited by Makoto Misono

Published
Oxford : Elsevier Science, 2013.
Physical Description
1 online resource (193 pages)
Additional Creators
Misono, M. (Makoto), 1939-
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Contents
Front Cover; Heterogeneous Catalysis of Mixed Oxides: Perovskite and Heteropoly Catalysts; Copyright; Contents; Preface; Chapter 1: Basis of Heterogeneous Catalysis; 1.1. Catalyst and Catalysis; 1.1.1. Rate and Equilibrium of Chemical Reaction and Role of Catalyst; 1.1.2. Three Essential Functions of Catalyst; 1.1.3. Essence of Catalytic Functions Based on Reaction Mechanism; 1.1.4. A Short History of Industrial Catalysts; 1.1.5. Classification of Catalysts; 1.1.6. Practical Applications of Catalysts; 1.1.7. Components and Shape of Industrial Catalysts, 1.2. Rate of Catalytic Reaction and Reaction Mechanism1.2.1. Reaction Rate; 1.2.2. Adsorption on Solid Surface; Rate and Isotherm; 1.2.3. Rate Equation of Catalytic Reaction; 1.2.3.1. Reaction of A+BC; L-H and E-R Mechanisms; 1.2.3.2. Other Mechanisms; 1.2.4. Reactor Type and Rate Expression; 1.2.5. Elucidation of Reaction Mechanism; 1.2.5.1. Rate Equation and Stoichiometry of Reaction; 1.2.5.2. Uses of Isotopes; 1.2.5.3. Direct Spectroscopic Observation of Reaction Intermediates Adsorbed on Catalyst; 1.2.5.4. Linear Free Energy Relationship (LFER); 1.2.5.5. Stereochemistry of Reaction, 1.2.5.6. Measurement of Rates of Reduction and Reoxidation of Catalyst1.2.6. Mass and Heat Transfer; 1.2.6.1. Effectiveness Factor; 1.2.6.2. Temperature Control; 1.2.7. Deactivation of Catalyst; 1.2.8. Comparison of Heterogeneous, Homogeneous and Biocatalysis; 1.3. Catalyst Design; 1.4. Preparation and Characterization of Catalysts; References; Chapter 2: Chemistry and Catalysis of Mixed Oxides; 2.1. Chemistry of Binary Oxides; 2.1.1. Structure of Binary Oxides (or Single Metal Oxides); 2.1.2. Lattice Defects and Nonstoichiometry (Berthollide Compounds), 2.1.3. Surface Structure of Single Metal Oxides2.1.4. Chemical Properties of Single Metal Oxides; 2.1.4.1. Acidity and Basicity; 2.1.4.2. Redox Properties; 2.1.5. Catalysis of Single Metal Oxides; 2.1.5.1. Acid-Base Catalysis; 2.1.5.2. Catalytic Oxidation and Hydrogenation-Dehydrogenation; 2.2. Chemistry of Mixed Oxides; 2.2.1. Structure of Mixed Oxides; 2.2.1.1. Crystal Structure of Mixed Oxides; 2.2.1.2. Surface Structure of Mixed Oxides; 2.2.2. Valence and Defects in Mixed Oxides; 2.2.3. Acidity and Basicity; 2.2.4. Redox Properties; 2.2.5. Mixed Oxides for Supports, and 2.3. Catalysis of Mixed Oxides2.3.1. Acid and Base Catalysis; 2.3.2. Oxidation Catalysis; 2.3.2.1. Complete Oxidation; 2.3.2.2. Selective Oxidation; 2.3.3. Hydrogenation, Dehydrogenation, and Metathesis; 2.4. Synergistic Effects in Mixed Oxide Catalysis; 2.4.1. Combination of Acid and Base Catalysis; 2.4.1.1. Concerted Action of Acid-Base Pair Sites; 2.4.1.2. Acidic and Basic Sites Functioning in Different Reaction Steps of Catalysis; 2.4.2. Combination of Dual Functions in Selective Oxidation; 2.4.2.1. Hydrogen Abstraction and Oxygen Addition Sites; 2.4.2.2. Acid and Oxidation Sites
Summary
Mixed oxides are the most widely used catalyst materials for industrial catalytic processes. The principal objective of this book is to describe systematically the mixed oxide catalysts, from their fundamentals through their practical applications. After describing concisely general items concerning mixed oxide and mixed oxide catalysts, two important mixed oxide catalyst materials, namely, heteropolyacids and perovskites, are taken as typical examples and discussed in detail. These two materials have several advantages: 1. They are, respectively, typical examples of salts of oxoa.
Subject(s)
ISBN
9780444538345 (electronic bk.)
0444538348 (electronic bk.)
Note
2.4.3. Roles of Catalyst Supports
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