Fluoropolymers 1: Synthesis [electronic resource] / edited by Gareth Hougham, Patrick E. Cassidy, Ken Johns, Theodore Davidson
- Topics in Applied Chemistry
- Synthesis -- Polyacrylates Containing the Hexafluoroisopropylidene Function in the Pendant Groups -- Fluoromethylene Cyanate Ester Resins -- Polymers from the Thermal (2? + 2?) Cyclodimerization of Fluorinated Olefins -- Functional Fluorpolymers and Fluoropolymers -- Use of Original Fluorinated Telomers in the Synthesis of Hybrid Silicones -- Chlorotrifluoroethylene Suspension Polymerization -- Fluorinated Polymers with Functional Groups -- Synthesis of Fluorinated Poly(Aryl Ether)s Containing 1,4-naphthalene Moieties -- Synthesis and Properties of Fluorine-containing Aromatic Condensation Polymers Obtained from Bisphenol AF and Its Derivatives -- Novel Fluorinated Block Copolymers -- Synthesis and Structure-property Relationships of Low-dielectric-constant Fluorinated Polyacrylates -- Epoxy Networks from a Fluorodiimidediol -- Synthesis of Fluoropolymers in Liquid and Supercritical Carbon Dioxide Solvent Systems -- Direct Fluorination -- Direct Fluorination of Polymers -- Surface Fluorination of Polymers Using Xenon Difluoride -- New Surface-fluorinated Products -- Modified Surface Properties of Technical Yarns -- Vapor Deposition -- Vapor Deposition Polymerization as a Route to Fluorinated Polymers -- Ultrathin PTFE, PVDF, and FEP Coatings Deposited Using Plasma-assisted Physical Vapor Deposition.
- The fluorine atom, by virtue of its electronegativity, size and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme high-performance applications have found their way into our homes, our clothing and even our language. Much progress has been made in understanding the sometimes confounding properties of fluoropolymers. Computer simulation is now contributing to this with new fluorine force fields and other parameters, bringing realistic prediction within reach of the practicing physical chemist. Fluoropolymers 1: Synthesis and Fluoropolymers 2: Properties attempt to bring together in one place the chemistry, physics and engineering properties of fluoropolymers. The collection was intended to provide balance between breadth and depth, with contributions ranging from the introduction of fluoropolymer structure-property relationships, to reviews of subfields, to more focused topical reports.
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