Fundamental Aspects of ELECTROCRYSTALLIZATION [electronic resource] / by J. O’M. Bockris, G. A. Razumney
- Author:
- Bockris, J. O'M. (John O'M.), 1923-2013
- Published:
- Boston, MA : Springer US, 1967.
- Physical Description:
- online resource
- Additional Creators:
- Razumney, G. A.
SpringerLink (Online service) - Access Online:
- ezaccess.libraries.psu.edu
- Contents:
- 1 Retrospect -- 1. The First Contributions -- 2. Earlier Concepts -- 2 Perspective -- 3 Methods of Investigation -- 1. Electrochemical Methods -- 2. Optical Methods -- 3. Surface and Solution Preparation -- 4 Basic Models of the Atomic Movements Which Lead to Deposition -- 1. A Definition -- 2. Mechanism of Interfacial Charge Transfer -- 3. The Alternative Paths for Metal Deposition -- 4. What Happens to the Hydration Sheath During the Atomic Movements Between Arrival in the Double Layer and Building into the Lattice? -- 5. Is Charge Transfer to all Types of Sites on the Metal Surface Equally Probable? -- 6. Can “Two-Electron Transfers” Take Place? -- 7. Adatom or Adion? -- 8. Path and Rate-Determining Step in Deposition: Theoretical Indications -- 5 Transients -- 1. Origin of Transient Measurements in Metal Deposition Studies -- 2. The Mehl and Bockris Analysis -- 3. Better Approximations in the Analysis of Transients -- 6 Discussion of Some Basic Questions Concerning Path and Rate-Determining Step -- 1. The Charge-Transfer Step -- 2. The Two Paths: Via the Surface or Directly to Kink Sites -- 3. The Generality of Rate Control by the Charge-Transfer Step at High Current Densities -- 4. Under Surface-Diffusion Control, Deposition Does Take Place Preferentially Near a Growth Site -- 7 Deposition and Dissolution Kinetics as a Function of the Initial Substrate -- 1. Variation of the Activity of a Surface with Time -- 2. The Effect of the Potential Dependence of the Activity of the Emergent Dislocations on the Kinetics of Deposition -- 3. The Effect of Change of Concentration of Emergent Dislocations in the Initial Substrate -- 8 Why Do Some Crystals Grow in Filamentary Shapes? -- 1. Crystal Growth, Dendritic Growth, and the Study of the Mechanism of Electrocrystallization -- 2. Facts about Dendritic Growth on Electrodes -- 3. Mechanism of Dendritic Growth -- 9 Mechanistic Aspects of Morphology -- 1. Preliminary Observations -- 2. Some Forms Observed -- 3. The Potential Dependence of the Growth Form -- 4. Impurity Effects on Morphology -- 5. Texture -- 10 Kinematics of Step Propagation -- 1. A Necessary Methodology -- 2. Microsteps -- 3. Macrosteps -- 4. Facts of Macrostep Movements -- 5. Determination of the Origin of Microsteps -- 6. The Instability of Bunches of Microsteps in the Absence of Impurities -- 7. Impurity Adsorption Theory of Bunching -- 8. Mechanism of the Propagation and Fading of Macrosteps -- 11 Effect of Adsorbed Substances upon Electrocrystallization -- 1. Facts -- 2. Adsorption of Inhibitors at Electrified Interfaces -- 3. Thermodynamics and Kinetics of Adsorption -- 4. Mechanisms of Inhibition -- 12 The Theory of the Electrochemical Leveling and Brightening of Surfaces -- 1. Factors Affecting Current Distribution -- 2. Leveling -- 3. Bright Electrocrystallization -- 13 Electrocrystallization and Crystallization from the Gas Phase -- 14 Prospects -- References.
- Subject(s):
- ISBN:
- 9781468406979
- Digital File Characteristics:
- text file PDF
- Note:
- AVAILABLE ONLINE TO AUTHORIZED PSU USERS.
View MARC record | catkey: 11944711