S Sulfur-Nitrogen Compounds Part 8 [electronic resource] : Compounds with Sulfur of Oxidation Number IV / by Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Reimund Jotter, Birgit Ledüc ; edited by Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Reimund Jotter, Alfons Kubny
- Author:
- Baumann, Norbert
- Published:
- Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 1991.
- Edition:
- 8th Edition.
- Physical Description:
- XXXI, 487 pages : online resource
- Additional Creators:
- Fachmann, Hans-Jürgen, Heibel, Brigitte, Jotter, Reimund, Ledüc, Birgit, Baumann, Norbert, Kubny, Alfons, and SpringerLink (Online service)
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- Series:
- Summary:
- PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.
- Subject(s):
- ISBN:
- 9783662063637
- Digital File Characteristics:
- text file PDF
- Note:
- AVAILABLE ONLINE TO AUTHORIZED PSU USERS.
- Part Of:
- Springer eBooks
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