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Theoretical evaluation of matrix effects on trapped atomic levels [electronic resource].

Published
Argonne, Ill. : Argonne National Laboratory, 1986.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description
Pages: 12 : digital, PDF file
Additional Creators
Argonne National Laboratory and United States. Department of Energy. Office of Scientific and Technical Information
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Summary
We suggest a theoretical model for calculating the matrix perturbation on the spectra of atoms trapped in rare gas systems. The model requires the ''potential curves'' of the diatomic system consisting of the trapped atom interacting with one from the matrix and relies on the approximation that the total matrix perturbation is a scalar sum of the pairwise interactions with each of the lattice sites. Calculations are presented for the prototype systems Na in Ar. Attempts are made to obtain ab initio estimates of the Jahn-Teller effects for excited states. Comparison is made with our recent Matrix-Isolation Spectroscopic (MIS) data. 10 refs., 3 tabs.
Report Numbers
E 1.99:anl/pprnt-89-96
anl/pprnt-89-96
Subject(s)
Other Subject(s)
Note
Published through SciTech Connect.
06/01/1986.
"anl/pprnt-89-96"
"DE89008448"
Gruen, D.M.; Das, G.P.
Funding Information
W-31109-ENG-38
View MARC record | catkey: 13806590