Mechanisms of iron-based catalysis investigated using model compounds [electronic resource].
- Published
- Washington, D.C. : United States. Dept. of Energy, 1994.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy. - Physical Description
- 5 pages : digital, PDF file
- Additional Creators
- Pacific Northwest Laboratory, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
Access Online
- Restrictions on Access
- Free-to-read Unrestricted online access
- Summary
- The catalytic mechanism of highly active, nanophase, iron-based coal liquefaction catalysts was investigated using a series of model compounds. The iron-oxide phases ferric oxyhydroxysulfate (OHS), 6-line ferrihydrite, hematite, and goethite, were evaluated as catalyst precursors with systematically substituted diphenylmethanes in the presence of a hydrogen donating solvent. The activity of the catalysts was observed to be dependent upon the functionality on the model compounds. The results of these model compound studies and their relationship to possible reaction mechanisms are presented.
- Report Numbers
- E 1.99:pnl-sa--24495
E 1.99: conf-940813--39
conf-940813--39
pnl-sa--24495 - Subject(s)
- Other Subject(s)
- Note
- Published through SciTech Connect.
08/01/1994.
"pnl-sa--24495"
" conf-940813--39"
"DE95007815"
208. American Chemical Society (ACS) national meeting, Washington, DC (United States), 21-26 Aug 1994.
Autrey, S.T.; Linehan, J.C.; Franz, J.A.; Darab, J.G.; Matson, D.W.; Camaioni, D.M. - Funding Information
- AC06-76RL01830
View MARC record | catkey: 13835288