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Design of a high activity and selectivity alcohol catalyst. Final status report and summary of accomplishments [electronic resource].

Published
Washington, D.C. : United States. Dept. of Energy, 1994.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description
88 pages : digital, PDF file
Additional Creators
University of Delaware, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
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Summary
This final DOE report for grant award number DE-FG22-90PC 90291 presents the results of our efforts to better understand the Rh-Mo/γ-Al₂O3 catalytic system for the hydrogenation of carbon monoxide and carbon dioxide to selectively form oxygenated products. The content of this report is divided into three major sections and a fourth, concluding section which addresses our major research accomplishments, as well as documents the most significant publications and presentations associated with this grant. The three main sections which make up the body of this report are presented in the in form of manuscripts which, in turn, summarize our progress in three areas of this project. The three body sections are organized as follows: Section I--Evidence for site isolation in Rh-Mo bimetallic catalysts derived from organometallic clusters; Section II--Surface Chemistry of Rh-Mo/γ-Al₂O₃: An analysis of surface acidity; and Section III--Comparative study of Rh/Al₂O₃ and Rh-Mo/Al₂O₃ Catalysts. Section IV summarizes major accomplishments. The content of this final report is meant to generally highlight our progress in both characterizing the nature of the Rh-Mo/Al₂O₃ system and probing its reactivity for insight on the oxygenate synergy present in this class of catalysts.
Report Numbers
E 1.99:doe/pc/90291--t13
doe/pc/90291--t13
Subject(s)
Other Subject(s)
Note
Published through SciTech Connect.
07/15/1994.
"doe/pc/90291--t13"
"DE95017768"
Mills, G.A.; Foley, H.C.
Funding Information
FG22-90PC90291
View MARC record | catkey: 13838714