Measurement of alkali in PFBC exhaust [electronic resource].
- Washington, D.C. : United States. Dept. of Energy, 1992. and Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Physical Description:
- 9 pages : digital, PDF file
- Additional Creators:
- Argonne National Laboratory, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
- Restrictions on Access:
- Free-to-read Unrestricted online access
- This project supports the DOE/METC Fossil Energy Program for the development of PFBC technology. Based on the analytical activated-bauxite sorber-bed technique, we are developing the RABSAM as an altemative to the on-line alkali analyzer for field application. As shown in Fig. 1, the RABSAM is a sampling probe containing a regenerable activated-bauxite adsorbent (RABA). It can be inserted directly into the PFBC exhaust duct and requires no HTHP sampling line. Alkali vapors are captured by the adsorbent purely through physical adsorption. The adsorbent is regenerated by a simple water-leaching process, which also recovers the adsorbed alkalis. The alkali analysis of the leachate by atomic absorption (AA) provides a basis for calculating the time-averaged alkali-vapor concentration in the PFBC exhaust. If the RABA is to use commercial grade activated bauxite, the clay impurities in activated bauxite can react with alkali vapors and, therefore, need to be either removed or deactivated. In earlier work, a 6M-LiCl-solution impregnation technique was shown to deactivate these impurities in fresh activated bauxite . During this year, RABA prepared by this technique was tested in a pressurized alkali-vapor sorption test unit to determine its NaCl-vapor capture efficiency and the regenerability of the sorbent by water extraction. Results of this study are presented and discussed.
- Published through SciTech Connect., 11/01/1992., "anl/cmt/cp--77193", " conf-921034--1", "DE93002900", 9. annual coal-fueled heat engines, advanced pressurized fluidized-bed combustion (PFBC), and gas stream cleanup systems contractors review meeting,Morgantown, WV (United States),27-29 Oct 1992., and Lee, S.H.D.; Swift, W.M.
- Funding Information:
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