Mild pyrolysis of selectively oxidized coals. [Quarterly] technical report, March 1, 1992--May 31, 1992 [electronic resource].
- Washington, D.C. : United States. Dept. of Energy, 1992. and Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Physical Description:
- 24 pages : digital, PDF file
- Additional Creators:
- Southern Illinois University at Carbondale, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
- The primary objective of this study is to investigate the removal organic sulfur from selectively oxidized Illinois coals using mild thermal/chemical processes. Work completed this quarter primarily concerned the investigation of the desulfurization of the selectively oxidized coals using aqueous or alcoholic base mixtures. Model compound studies were initiated. Results were: Levels of desulfurization obtained in this study are at, or very close to, the 90% removal levels required for these coals to be in compliance with the Clean Air Act legislation; Up to 89.4% of the sulfur in the IBC 101 coal and 88.9% of the sulfur in the IBC 106 coal has been removed by combining selective oxidation and alcoholic/base reactions; Overall, selective oxidation pretreatment always led to a lower sulfur product than the untreated sample; Substantial enhancement in the reactivity of the sulfur in the coal has been achieved by the selective oxidation pretreatment; The highest levels of desulfurization obtained so far all involve bases as additives; The water/Na₂CO₃ combination, was superior than any of the aqueous hydroxide bases. Possible synergistic interactions between the alcohol and the base are suspected. Over 70% of the sulfur in the IBC 101 coal can be removed by performing vacuum pyrolysis on the selectively oxidized coal. Lower sulfur contents are obtained by lowing the pyrolysis pressure.
- Published through SciTech Connect., 10/01/1992., "doe/pc/91334--t71", "DE93000521", and Palmer, S.R.; Hippo, E.J.
- Type of Report and Period Covered Note:
- Quarterly; 04/01/1992 - 06/30/1992
- Funding Information:
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