Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction [electronic resource].
- Washington, D.C. : United States. Dept. of Energy, 1986. and Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Physical Description:
- Pages: (13 pages) : digital, PDF file
- Additional Creators:
- SRI International, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
- Restrictions on Access:
- Free-to-read Unrestricted online access
- The objective of this project is to identify, prepare, test, characterize, and evaluate a practical, homogeneous catalyst for a water-gas shift process. The project effort is divided into the following five tasks: (1) Update SRI's recent review of the literature on the catalysis of the water-gas shift reaction (WGSR) to include references after 1982 and those in the patent literature. Based on this review, SRI will choose ten candidate systems to be evaluated as to their abilities to catalyze the WGSR using syngas derived from gasified coal. (2) Develop a test plan designed to effectively evaluate both the catalysts and, to some extent, reactor configuration for WGSR catalysis. (3) Perform a series of experiments to identify the most effective and economical of the ten candidate catalysts and then further evaluate the reaction kinetics of at least one selected catalyst system to develop sufficient data to provide the basis for the work in Task 4. (4) Develop a mathematical model of the final candidate system that uses rate expressions to describe the catalytic process. (5) Perform a techno-economical evaluation of the catalyst in terms of a proposed plant design based on the reaction model, current costs, and standard chemical engineering practice and compare the proposed design with a conventional hydrogen plant.
- Published through SciTech Connect., 04/01/1986., "doe/mc/22065-t15", "DE92017716", and Wood, B.J.; Krishnan, G.N.; Laine, R.M.
- Funding Information:
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