The single electron chemistry of coals, January 1, 1990--March 30, 1990 [electronic resource].
- Washington, D.C. : United States. Dept. of Energy, 1990.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Physical Description:
- Pages: (14 pages) : digital, PDF file
- Additional Creators:
- Lehigh University
United States. Department of Energy
United States. Department of Energy. Office of Scientific and Technical Information
- The Wyodak, Upper Freeport and Pocahontas No. 3 samples containing DPPD display a decrease in spin density as compared to the starting coals. Coincident with this decrease is a loss or decrease of the narrow inertinite signal in the esr spectrum of these coals. The Pittsburgh No. 8 coal sample containing DPPD also displays a loss of spin density as compared to the starting coal but there is no change in the esr spectrum. These results compare well with earlier work involving 4-vinylpyridine and the same coal samples. We discovered the presence of poly(4-vinylpyridine) in our coal samples and a concurrent loss of inertinite radical density. It is possible that the inertinite radicals may initiate the polymerization or in the present work may abstract hydrogen from DPPD. No C=N stretch was displayed in the IR spectrum to substantiate this claim.
- Published through SciTech Connect.
Larsen, J.W.; Flowers, R.A. II.
- Funding Information:
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