Actions for Electrolytes : supramolecular interactions and non-equilibrium phenomena in concentrated solutions

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Electrolytes : supramolecular interactions and non-equilibrium phenomena in concentrated solutions / Georgii Georgievich Aseyev

Author
Aseev, G. G. (Georgiĭ Georgievich)
Published
Boca Raton, FL : CRC Press, [2015]
Physical Description
xvii, 345 pages ; 25 cm

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Contents
Machine generated contents note: SECTION I Supramolecular Interactions -- ch. 1 Historic Introduction -- 1.1.Early Views on the Process of Ion Solvation in Electrolyte Solutions -- 1.2.Evolution of Solvation Concepts and Structural State of Electrolyte Solutions -- References -- ch. 2 Supramolecular Designing of a Host -- 2.1.Stages of Formation of Approaches to the Concept of Long-Range Supermolecular Forces -- 2.2.Principles of Supramolecular-Thermodynamic Approach -- 2.3.Quantum Statistics of Supermolecular Interactions -- 2.4.Supramolecular Host--Guest Structure Distribution Function -- 2.5.Rate of Distribution Function Change in Time -- 2.5.1.Equations of Motion -- 2.6.Supramolecular Interactions Potential -- 2.6.1.Maxwell's Equations -- 2.7.Solving the Equation for Potential in the Absence of External Fields -- References -- ch. 3 Thermodynamics of Supermolecular and Supramolecular Interactions -- 3.1.Supermolecular--Thermodynamic Interactions of Activity Coefficients -- 3.2.Guest Activity Function -- 3.3.Minimum Interaction Distance of Electrostatic Forces among Ions in the Host Solution -- 3.4.Distance between Ions in the Host Solution -- 3.5.Dielectric Permittivity of Host--Guest Solution -- References -- ch. 4 Supermolecular Interactions -- 4.1.van der Waals Components of Attraction Potential -- 4.1.1.Perturbation Operator -- 4.1.2.Interaction of Two Dipoles -- 4.2.Perturbation Method -- 4.3.Interaction Energy in the First Approximation of the Perturbation Method -- 4.3.1.Interaction of Two Molecular Dipoles -- 4.3.2.Averaging over Orientations -- 4.3.3.Other Expansion Terms of Interaction Energy as a Series in Powers R-1 -- 4.3.4.Polarization (Induction) Interdipole Interactions -- 4.3.5.Dispersion (London) Interactions -- 4.4.Evaluation of the Energy of van der Waals Interactions in Structure Formation of the Guest--Host Solution -- 4.5.Ion--Dipole Interactions in the First Approximation of the Perturbation Theory -- 4.6.Weak Chemical Interactions in the Host Solution -- 4.7.Short-Range Repulsion in the Host Solution -- 4.7.1.Other Model Potentials -- 4.7.1.1.Hard Sphere -- 4.7.1.2.Point Center of Repulsion -- 4.7.1.3.Rectangular-Well Potential -- 4.7.1.4.Model of Triangular-Well Potential -- 4.7.1.5.Sutherland Model -- 4.7.1.6.Buckingham Potential -- 4.7.1.7.Kihara Spherical Model (Spherical Core Model) -- 4.8.Adjustment of Potential of Supramolecular Interactions -- 4.9.Thermodynamics of Water Activity Interaction -- References -- SECTION II Non-Equilibrium Phenomena -- ch. 5 Electrical Conductivity -- 5.1.Historic Preamble -- 5.2.Theories of Electrical Conductivity -- 5.3.General Continuity Equation for Electrolyte Solutions in Perturbed State -- 5.4.Electrical Conductivity: General Theory of Supermolecular Forces -- 5.5.Relaxation Force -- 5.6.Electrophoretic Retardation -- 5.7.Electrical Conductivity of Electrolytes at Weak Electric Fields and Low Frequencies -- 5.8.Results and Their Discussion -- References -- ch. 6 Viscosity -- 6.1.Semiempirical Approaches to Viscosity Determination -- 6.1.1.Multicomponent Solutions -- 6.2.Viscosity Theory -- 6.3.General Theory of Viscosity -- 6.4.Solution Viscosity Coefficient (General Solving) -- 6.5.Solution Viscosity Coefficient (Final Solving) -- References -- ch. 7 Diffusion Coefficient -- 7.1.Introduction -- 7.2.About Diffusion Theories -- 7.3.Diffusion Flows -- 7.4.General Theory of Supermolecular Forces in Diffusion Flows -- 7.5.Diffusion Coefficient (Final Solution) -- References.
Subject(s)
ISBN
9781482249385 hardcover
1482249383 hardcover
Bibliography Note
Includes bibliographical references and index.
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