Detailed chemical kinetic models for large n-alkanes and iso-alkanes found in conventional and F-T diesel fuels [electronic resource].
Published
Washington, D.C. : United States. Dept. of Energy, 2009. Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
n-Hexadecane and 2,2,4,4,6,8,8-heptamethylnonane represent the primary reference fuels for diesel that are used to determine cetane number, a measure of the ignition property of diesel fuel. With the development of chemical kinetics models for both primary reference fuels, a new capability is now available to model diesel fuel ignition. Additionally, we have developed chemical kinetic models for a whole series of large n-alkanes and a large iso-alkane to represent these chemical classes in fuel surrogates for conventional and future fuels. These chemical kinetic models are used to predict the effect of the aforementioned fuel components on ignition characteristics under conditions found in internal combustion engines.
Published through SciTech Connect. 03/09/2009. "llnl-conf-411174" Presented at: U. S. National Combustion Meeting, Ann Arbor, MI, United States, May 17 - May 20, 2009. Pitz, W J; Westbrook, C K; Curran, H J; Mehl, M.