Actions for Adsorption sites in zeolites A and X probed by competitive adsorption of H{sub 2} with N{sub 2} or O{sub 2} [electronic resource] : implications for N{sub 2}
Adsorption sites in zeolites A and X probed by competitive adsorption of H{sub 2} with N{sub 2} or O{sub 2} [electronic resource] : implications for N{sub 2}/O{sub 2} separation
Published
Washington, D.C. : United States. Dept. of Energy, 1998. Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
We determine details of the adsorption of O₂ or N₂ in Na⁺ and Li⁺ exchanged zeolites by way of their effect on coadsorbed H₂ molecules using inelastic neutron scattering (INS) techniques. Adsorption site occupancies are deduced with the aid of MC simulations. The expected stronger binding of N₂ (compared with O₂) in LiX is evident in coadsorption spectra of N₂ or O₂ with H₂.
Published through SciTech Connect. 08/31/1998. "anl/ipns/cp-95673" 12th International Zeolite Conference, Baltimore, MD (US), 07/05/1998--07/10/1998. Eckert, J.