The Reaction Mechanism of Decomposing Chloroform by Bi-Metal Nano-Metallic Particles of Fe/Ni [electronic resource].

Published: Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2004.
Physical Description: vp : digital, PDF file
Additional Creators: United States. Department of Energy. Office of Scientific and Technical Information

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Summary

By adding Ni into the production of Fe/Ni nano-metallic particles, the acceleration of reduction ability of particles to decompose Chloroform is observed. The addition also could inhibit the shielding effect of pure iron compounds. This research studied the production and properties of the nano-particle metallic compounds of Fe and Ni, the decomposition of Chloroform by the particles and the mechanism of the decomposition processes. The experimental results indicated effective and rapid decomposition of chloroform by the Fe/Ni nano-particles on aluminum oxides, comparing to nano particles of iron in other researches. The reaction mechanism of Fe/Ni particles was pseudo first order with the half life about 0.7 hour, which was much shorter than the nano-Fe particles.

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E 1.99:826125

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Published through SciTech Connect.
03/31/2004.
227th American Chemical Society Meeting, Anaheim, CA (US), 03/28/2004--04/01/2004.
Horng, Jao-Jia; Hsieh, Su-Hwei.
National Yulin University of Science and Technology, Touliou (TW)
Sponsor not identified (US)

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