Groundwater at the Bear Creek Valley Characterization Area, located at the Oak Ridge Y-12 Plant, is contaminated with regulated metals and volatile organic compounds (VOCs) due to former site activities and disposal practices. The contaminant of principle concern, from the perspective of protecting human health, is soluble uranium, which is present in some waters at concentrations up to a few parts-per-million. We present product speciation and relative reaction kinetics; for removal of soluble uranium under oxic and anoxic conditions with use of zero-valent iron. Under oxic conditions, U(VI) is rapidly and strongly sorbed to hydrous ferric oxide particulate ({open_quotes}rust{close_quotes}), whereas uranium is slowly and incompletely reduced to U(IV) under anoxic conditions.
Published through SciTech Connect. 12/31/1997. "conf-970208--proc." "DE98001967" International containment technology conference and exhibition, St. Petersburg, FL (United States), 9-12 Feb 1997. Bostick, W.D.; Fiedor, J.N.; Jarabek, R.J. USDOE, Washington, DC (United States)