Final Technical Report for grant entitled "New Horizons in C-F Activation by Main Group Electrophiles" [electronic resource].
- Published
- Washington, D.C. : United States. Dept. of Energy, 2014.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy. - Physical Description
- 1.5 MB : digital, PDF file
- Additional Creators
- Brandeis University, United States. Department of Energy, United States. Department of Energy. Office of Basic Energy Sciences, and United States. Department of Energy. Office of Scientific and Technical Information
Access Online
- Restrictions on Access
- Free-to-read Unrestricted online access
- Summary
- We became interested in developing new methods for hydrodefluorination (HDF) and other types of C-F bond conversion in polyfluoroalkanes under mild conditions. We were attracted to an approach to C-F activation, where the key C-F cleavage proceeds by a Lewis acid abstraction of fluoride rather than a redox event. The efforts during the previous period were aimed at a) advancing the HDF reactivity with improvement in scope and catalyst longevity; b) extending C-F activation beyond HDF; c) generating insight about the elementary steps of the reaction and potential intermediates.
- Report Numbers
- E 1.99:doe-brandeis-15815
doe-brandeis-15815 - Subject(s)
- Note
- Published through SciTech Connect.
01/16/2014.
"doe-brandeis-15815"
Ozerov, Oleg V; Ozerov, Oleg V. - Type of Report and Period Covered Note
- Final; 08/15/2006 - 12/31/2009
- Funding Information
- FG02-06ER15815
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