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Synthetic and Thermodynamic Investigations of Ancillary Ligand Influence on Catalytic Organometallic Systems. Final Report [electronic resource].

Published
Washington, D.C. : United States. Dept. of Energy. Office of Energy Research, 2003.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description
5 pages : digital, PDF file
Additional Creators
United States. Department of Energy. Office of Energy Research and United States. Department of Energy. Office of Scientific and Technical Information
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Summary
During the grant period we have been involved in synthesizing and experimentally determining solution enthalpy values associated with partially fluorinated ligands. This has lead to the publication of manuscripts dealing with synthetic, calorimetric and catalytic behavior of partially fluorinated ligands. The collaboration with Los Alamos researchers has lead to the publication of catalytic results in sc CO₂ which have proven very interesting. Furthermore, we have also examined ligands that behave as phosphine mimics. The N-heterocyclic carbenes have been explored as alternatives for tertiary phosphines and have resulted in the design and construction of efficient palladium and nickel system capable of performing C-C and C-N cross coupling reactions. The initial studies in this areas were made possible by exploratory work conducted under the DOE/EPSCoR grant.
Report Numbers
E 1.99:821151
Subject(s)
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Note
Published through SciTech Connect.
03/20/2003.
Nolan, Steven.
University of New Orleans, New Orleans, LA (US)
Type of Report and Period Covered Note
Final; 03/20/2003 - 03/20/2003
Funding Information
FG02-98ER45732
View MARC record | catkey: 14393566