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Model studies of hydrodesulfurization by Mo. Annual technical progress report, December 1, 1991--November 30, 1992 [electronic resource].

Published:
Washington, D.C. : United States. Dept. of Energy, 1992.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description:
8 pages : digital, PDF file
Additional Creators:
Harvard University, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
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Summary:
Effects of surface modifiers (Co, S) on activity and selectivity of Mo(110) for desulfurization processes were studied. S generally increases the selectivity for desulfurization while decreasing overall reactivity. Co promots C-H activation processes on Mo(110). The Mo(110)-(9x2)-Co surface affects the desulfurization of 2,5- dihydrothiophene and methanethiol. Vibrational spectroscopy is being used for determining molecular orientation; vibrational frequencies were calculated for four labeled 2-propoxide isomers on Mo(110) and found to agree with experiment.
Report Numbers:
E 1.99:doe/er/13289--6
doe/er/13289--6
Subject(s):
Other Subject(s):
Note:
Published through SciTech Connect.
11/01/1992.
"doe/er/13289--6"
"DE93002774"
Friend, C.M.
Type of Report and Period Covered Note:
Annual; 01/01/1991 - 12/31/1992
Funding Information:
FG02-84ER13289
View MARC record | catkey: 14394800