Actions for [Comparison of group transfer, inner shere and outer sphere electron transfer mechanisms for organometallic complexes]. Summary [electronic resource].

Email RIS file
Bookmark
Report an Issue

[Comparison of group transfer, inner shere and outer sphere electron transfer mechanisms for organometallic complexes]. Summary [electronic resource].

Published
Washington, D.C. : United States. Dept. of Energy, 1991.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description
4 pages : digital, PDF file
Additional Creators
United States. Department of Energy and United States. Department of Energy. Office of Scientific and Technical Information
Access Online

Availability

I Want It
I Want It

Finding items...

Restrictions on Access
Free-to-read Unrestricted online access
Summary
Our studies of reactions of metal carbonyl cations and anions have shown that metal carbonyl cations can catalyze CO exchange reactions on metal carbonyl anions. This result provides further evidence for a mechanism involving attack of the metal carbonyl anion on a carbon of the metal carbonyl cation in CO{sup 2+} transfer reactions. Reaction of metal carbonyl anions with metal carbonyl halides is a common approach to formation of metal-metal bonds. We have begun to use kinetic data and product analysis to understand the formation of homobimetallic versus heterobimetallic products in such reactions. Initial data indicate a nucleophilic attack, possibly through a ring-slippage mechanism.
Report Numbers
E 1.99:doe/er/13775--4
doe/er/13775--4
Subject(s)
Other Subject(s)
Note
Published through SciTech Connect.
12/31/1991.
"doe/er/13775--4"
"DE92004068"
State Univ. of New York, Buffalo, NY (United States)
Type of Report and Period Covered Note
Annual; 12/31/1991 - 12/31/1991
Funding Information
FG02-87ER13775
View MARC record | catkey: 14394874