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Pulsed laser kinetic studies of liquids under high pressure. Progress report, November 25, 1991--September 18, 1992 [electronic resource].

Published:
Washington, D.C. : United States. Dept. of Energy, 1992.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description:
7 pages : digital, PDF file
Additional Creators:
University of Utah, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
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Summary:
A laser flash photolysis kinetic study of 2,2′-bipyridine bidentate chelating ligands with one claw in the first coordination sphere of a molybdenum carbonyl complex has been completed at pressures up to 150 MPa. The reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2′-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Stability constants for lithium ion complexes with crown ethers in a room temperature molten salt, fluorescence quantum yields for cresyl violet and several other dyes in solution, and the oxidation of alcohols by OsO₄ have also been investigated.
Report Numbers:
E 1.99:doe/er/13227--t4
doe/er/13227--t4
Subject(s):
Other Subject(s):
Note:
Published through SciTech Connect.
09/22/1992.
"doe/er/13227--t4"
"DE93000884"
Eyring, E.M.
Type of Report and Period Covered Note:
Annual; 01/01/1991 - 12/31/1992
Funding Information:
FG02-84ER13227
View MARC record | catkey: 14395357