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A shock tube study of the reactions of the hydroxyl radical with combustion species [electronic resource].

Published
Washington, D.C. : United States. Dept. of Energy, 1991.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description
Pages: (5 pages) : digital, PDF file
Additional Creators
Aerospace Corporation, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
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Summary
The reactions of OH radicals with hydrocarbons have received a great deal of attention in recent years because of these processes are principal steps in the oxidation of organic fuels -- whether occurring in combustion/propulsion systems, in the atmosphere, or elsewhere. Of the various radicals capable of attacking hydrocarbons, OH radicals are generally the most reactive, and their reactions directly yield water molecules, one of the major final oxidation products. In the atmosphere, the combined effect of the OH radical's reactivity and concentration make it the single species that determines the atmospheric lifetime of an organic substance. The principal goals of the kineticist in the field of oxidation chemistry are (1) to measure as many elementary reaction rate coefficients as are conveniently studied in the laboratory; and (2) to develop theoretical and/or semiempirical tools for extrapolating from measured rate coefficients to unmeasured ones. The latter step is necessary because of the sheer number of reactions of possible interest.
Report Numbers
E 1.99:doe/er/13812-t1
doe/er/13812-t1
Subject(s)
Other Subject(s)
Note
Published through SciTech Connect.
05/21/1991.
"doe/er/13812-t1"
"DE92012573"
Cohen, N.
Funding Information
FG03-87ER13812
View MARC record | catkey: 14395533