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Gas-phase generations and rearrangement of silathiones, R sub 2 Si=S [electronic resource].

Published:
Washington, D.C : United States. Dept. of Energy. Office of Energy Research, 1991.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description:
Pages: (102 pages) : digital, PDF file
Additional Creators:
Ames Laboratory, United States. Department of Energy. Office of Energy Research, and United States. Department of Energy. Office of Scientific and Technical Information
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Summary:
Three routes are explored for the generation of silathiones: (1) the retroene elimination of propene from allythiodimethylsilane and 1-allythio-1-hydrido-1,2,2,2-tetramethylsilane; (2) the reaction of silylene, Me₂Di, with carbon disulfide which is thought to form a transient 3-membered ring with CS₂ and the elimination of carbon disulfide to produce diethylsilathione; and (3) the beta-elimination of bis(trimethylsilythio)dimethylsilane. All these methods are explored in some detail. A second example of a silathione-silylene isomerization was observed in the pyrolysis of 1,1-bis(trimethylsilythio)-1,2,2,2-tetramethyldisilane. 89 refs., 5 figs., 10 tab. (BM)
Report Numbers:
E 1.99:is-t-1508
is-t-1508
Subject(s):
Other Subject(s):
Note:
Published through SciTech Connect.
01/08/1991.
"is-t-1508"
"DE91007524"
Kim, Chong Bok.
Funding Information:
W-7405-ENG-82
View MARC record | catkey: 14395551