Potentiometric studies at ORNL with hydrogen electrode concentration cells [electronic resource].

Published:: Washington, D.C. : United States. Dept. of Energy, 1994.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description:: 10 pages : digital, PDF file
Additional Creators:: Oak Ridge National Laboratory, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information

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Summary:

The absence of suitably stable reference electrodes for and to 300 C led ORNL to develop hydrogen electrode concentration cells for studies of equilibria of interest in reactor and steam generator systems to about 300 C during the late 1960`s and seventies. During the intervening two dozen years over twenty scientists have participated in potentiometric studies at Oak Ridge and much of that work will be summarized in this paper. A description of hydrogen electrode concentration cells developed in the late sixties and currently in use at Oak Ridge is given. The method of measurement, data interpretation, and published results are reviewed for studies of acid-base ionization, metal ion hydrolysis, and metal complexation reactions using principally such cells in titration or flow modes. 41 refs.

Report Numbers:

E 1.99:conf-9409219--3
conf-9409219--3

Subject(s):

Inorganic, Organic, Physical And Analytical Chemistry

Other Subject(s):

Note:

Published through SciTech Connect.
12/31/1994.
"conf-9409219--3"
"DE95006742"
""
12. International conference on properties of water and steam,Orlando, FL (United States),11-16 Sep 1994.
Palmer, D.A.; Wesolowski, D.J.; Mesmer, R.E.

Funding Information:

AC05-84OR21400

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