Determining yttrium in plutonium by anion-exchange x-ray fluorescence [electronic resource].
- Los Alamos, N.M. : Los Alamos National Laboratory, 1985. and Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Physical Description:
- Pages: 5 : digital, PDF file
- Additional Creators:
- Los Alamos National Laboratory and United States. Department of Energy. Office of Scientific and Technical Information
- This report describes a method for determining yttrium in plutonium using an anion-exchange separation and x-ray fluorescence. We add zirconium to the plutonium solution as an internal standard. We oxidize the plutonium to Pu + 4 and pass the solution through an anion-exchange column with 8M HCl. The Pu + 4 sorbs to the resin and the yttrium and zirconium pass through completely. We evaporate the eluate solution containing the yttrium and zirconium and transfer it to a 10-ml volumetric flask. We add a portion of this solution to an x-ray cell and measure the Ka x-ray line for both yttrium and zirconium. The ratio of yttrium to zirconium is then compared with standards. This method has a precision of 0.84% relative standard deviation for yttrium over a concentration range of 0.5 to 3.5 mg in a 10-ml volume. 1 ref., 2 figs., 2 tabs.
- Published through SciTech Connect., 11/01/1985., "la-10544", "DE86005840", and Martell, C.J.; Hansel, J.M.
- Funding Information:
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