Quality engineering and control. Semiannual progress report, May-October 1978 [electronic resource].
- Downey, Calif : Rockwell International, 1979. and Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Physical Description:
- Pages: 26 : digital, PDF file
- Additional Creators:
- Rockwell International and United States. Department of Energy. Office of Scientific and Technical Information
- Restrictions on Access:
- Free-to-read Unrestricted online access
- The standard colorimetric procedure for thorium was improved by using lanthanum carrier precipitation of thorium fluoride, conversion to sulfate, and colorimetric measurement with thoron. Four types of anion-exchange resins were evaluated using breakthrough capacity, elution volume, and the neptunium-plutonium ratios in both wash solutions and ion-column eluates as criteria, and 100 to 200 mesh Dowex 1 x 4 resin had the most favorable separation characteristics. Use of commercially available aqueous cleaner followed by water and acetone rinses was found to be superior to other techniques for cleaning uranium samples prior to carbon analysis. The substitution of sodium bisulfate for potassium pyrosulfate in the fusion procedure has lead to a more efficient dissolution process for oxide samples undergoing plutonium assay and the determination of uranium impurities. Sealed-capillary differential thermal analysis experiments were performed to assess the relative reactivities of iron, stainless steel, copper, beryllium, aluminum, and plutonium with trichloroethylene, methyl chloroform, and Freon TF. Results obtained by a method involving reduction of plutonium with titanium (III) chloride followed by titration with standard cerium (IV) sulfate solution are comparable to those obtained by an established amperometric-titration method.
- Published through SciTech Connect., 08/20/1979., "rfp-2840", and Carpenter, R.L.
- Funding Information:
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