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K Basin sludge polychlorinated biphenyl removal technology assessment [electronic resource].

Published
Washington, D.C. : United States. Dept. of Energy, 1998.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description
68 pages : digital, PDF file
Additional Creators
United States. Department of Energy and United States. Department of Energy. Office of Scientific and Technical Information
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Summary
The two Hanford K Basins are water-filled concrete pools that contain over 2,100 metric tons of N Reactor fuel elements stored in aluminum or stainless steel canisters. During the time the fuel has been stored, approximately 50 m3 of heterogeneous solid material have accumulated in the basins. This material, referred to as sludge, is a mixture of fuel corrosion products, metallic bits of spent fuel and zirconium clad iron and metal corrosion products and silica from migrating sands. Some of the sludges also contain PCBs. The congener group of PCBs was identified as Aroclor 1254. The maximum concentration of sludge PCBS was found to be 140 ppm (as settled wet basis). However, the distribution of the PCBs is non-uniform throughout the sludge (i.e., there are regions of high and low concentrations and places where no PCBs are present). Higher concentrations could be present at various locations. Aroclors 1016/1242, 1221, 1248, 1254, and 1260 were identified and quantified in K West (KW) Canister sludge. In some of these samples, the concentration of 1260 was higher than 1254. The sludge requires pre-treatment to meet tank farm waste acceptance criteria, Among the numerous requirements, the sludge should be retreated so that it does not contain regulated levels of Toxic Substances Control Act (TSCA) compounds. Because of their stable chemistry and relative insolubility in water, PCBs are difficult to treat. They also resist degradation from heat and electrical charges. This stability has resulted in environmental persistence which has prompted the development of a variety of new cleanup processes including supercritical processes, advanced oxidation, dehalogenation and others. Hopefully, most of the new processes are discussed herein. Information on new processes are being received and will be evaluated in a future revision.
Report Numbers
E 1.99:hnf--3095
hnf--3095
Subject(s)
Other Subject(s)
Note
Published through SciTech Connect.
08/25/1998.
"hnf--3095"
"DE99050961"
"EW7040000"
Ashworth, S.C.
Fluor Daniel Hanford Inc., Richland, WA (United States)
Type of Report and Period Covered Note
Topical; 08/01/1998 - 08/01/1998
Funding Information
AC06-96RL13200
View MARC record | catkey: 14413427