Email RIS file
Bookmark
Report an Issue

Technical Status Report on the Effect of Phosphate and Aluminum on the Development of Amorphous Phase Separation in Sodium [electronic resource].

Published
Washington, D.C. : United States. Dept. of Energy, 1998.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
Physical Description
vp : digital, PDF file
Additional Creators
United States. Department of Energy. Savannah River Site, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
Access Online

Availability

I Want It
I Want It

Finding items...

Restrictions on Access
Free-to-read Unrestricted online access
Summary
The objective of the Tank Focus Area ''Optimize Waste Loading'' task is to enhance the definition of the acceptable processing window for high-level waste vitrification plants. One possible manner in which the acceptable processing window may be enhanced is by reducing the uncertainty of various compositional/property models through a specifically defined experimental plan. A reduction in model uncertainty can reduce limitations on current acceptance constraints and may allow for a larger processing or operational window. Enhanced composition/property model predictions coupled with an increased waste loading may decrease the processing time and waste glass disposal costs (i.e., overall lifecycle costs). One of the compositional/property models currently being evaluated by the Tanks Focus Area is related to the development of amorphous phase separation in multi-component borosilicate glasses.Described in this report is the current status for evaluating the effect of phosphorus and alumina on both simple sodium borosilicate and high-level waste glasses on the formation of amorphous phase separation. The goal of this subtask is to increase the understanding of the formation of phase separation by adding significant amounts (3-5 wt. percent) of phosphorus and alumina to well-characterized glasses. Additional scope includes evaluating the effects of thermal history on the formation of amorphous phase separation and durability of select glasses.The development of data, understanding, and quantitative description for composition and kinetic effects on the development of amorphous phase separation will continue in FY99. This effort will provide insight into the compositional and thermal effects on phase stability and will lead to a better understanding of the methods used to predict the development of amorphous phase separation in HLW glasses.
Report Numbers
E 1.99:wsrc-tr-98-00327, rev. 0
wsrc-tr-98-00327, rev. 0
Subject(s)
Other Subject(s)
Note
Published through SciTech Connect.
11/03/1998.
"wsrc-tr-98-00327, rev. 0"
Cozzi, A.D.
Type of Report and Period Covered Note
Annual; 11/03/1998 - 11/03/1998
Funding Information
AC09-96SR18500
View MARC record | catkey: 14414502