MELTING OF GLASS BATCH - MODEL FOR MULTIPLE OVERLAPPING GAS-EVOLVING REACTIONS [electronic resource].
- Washington, D.C. : United States. Dept. of Energy. Office of Environmental Management, 2012.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Additional Creators:
- Hanford Site (Wash.)
United States. Department of Energy. Office of Environmental Management
United States. Department of Energy. Office of Scientific and Technical Information
- In this study, we present a model for the kinetics of multiple overlapping reactions. Mathematical representation of the kinetics of gas-evolving reactions is crucial for the modeling of the feed-to-glass conversion in a waste-glass melter. The model simulates multiple gas-evolving reactions that occur during heating of a high-alumina high-level waste melter feed. To obtain satisfactory kinetic parameters, we employed Kissinger's method combined with least-squares analysis. The power-law kinetics with variable reaction order sufficed for obtaining excellent agreement with measured thermogravimetric analysis data.
- Published through SciTech Connect.
"orp-51803 rev 0"
Pre-Publication to Journal of Thermal Analysis and Calorimetry
KRUGER AA; HRMA PR; PIERCE DA; POKORNY R.
- Funding Information:
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