Plutonium (iv) complexes of mixed pyridine n-oxide and phosphinoxide f-element extractants [electronic resource].
- Washington, D.C. : United States. Dept. of Energy, 2003. and Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy.
- Physical Description:
- 8 unnumbered pages : digital, PDF file
- Additional Creators:
- Los Alamos National Laboratory, United States. Department of Energy, and United States. Department of Energy. Office of Scientific and Technical Information
- Restrictions on Access:
- Free-to-read Unrestricted online access
- Analytical and bulk scale separation and processing of aqueous acidic solution s containing f-element ions are regularly accomplished using liquid-liquid extraction (LLE) methods that employ a neutral organic donor ligand dissolved in an organic phase . 1-5 Several monofunctional ligands have been used as LLE reagents, but all display one or more deficiencies1 'S due to the chemical similarity of the tri valent lanthanides (Ln) to th e trivalent actindes (An) . Since the trivalent 4f and 5f ions have identical charges, chemical separation agents for these two groups need to differentiate among these har d cations based on their size or chemical bonding preferences . This task is not easy since, as a consequence of the lanthanide and actinide contractions, the Ln and An fission products which need to be separated have similar ionic radii . In order to develop new ligands for the separation process, we must have a fundamental understanding of how these separation agents interact with both Ln and An ions on a molecular level.
- Published through SciTech Connect., 01/01/2003., "la-ur-03-0748", Submitted to: Plutonium Futures Conference. Marriott Hotel, Albuquerque, NM, July 6-10, 2003., and Scott, B. L.; Neu, M. P.; Matonic, J. H.; Enriquez, A. E.; Paine, R. T.
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