Actions for Regeneration and recycle of spent oxide reduction solvent salts used in pyrochemical plutonium recovery operations at Los Alamos [electronic resource].
Regeneration and recycle of spent oxide reduction solvent salts used in pyrochemical plutonium recovery operations at Los Alamos [electronic resource].
- Published
- Los Alamos, N.M. : Los Alamos National Laboratory, 1986.
Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy. - Physical Description
- Pages: 7 : digital, PDF file
- Additional Creators
- Los Alamos National Laboratory and United States. Department of Energy. Office of Scientific and Technical Information
Access Online
- Restrictions on Access
- Free-to-read Unrestricted online access
- Summary
- One method used at Los Alamos for producing plutonium metal is to chemically reduce the oxide with calcium metal in molten CaCl/sub 2/ at 850/sup 0/C. The solvent CaCl/sub 2/ from this reduction step is currently discarded as low-level radioactive waste because it is saturated with the reaction by-product, CaO. We have developed and demonstrated a molten salt technique for rechlorinating the CaO, thereby regenerating the CaCl/sub 2/ and incorporating solvent recycle into the batch PuO/sub 2/ reduction process. We discuss results from salt regeneration and recycle experiments, and present our plans for incorporating the technique into an advanced design for semi-continuous plutonium metal production.
- Report Numbers
- E 1.99:la-ur-86-273
E 1.99: conf-860603-4
conf-860603-4
la-ur-86-273 - Subject(s)
- Other Subject(s)
- Calcium Chlorides
- Recycling
- Calcium Oxides
- Chlorination
- Experimental Data
- Molten Salts
- Pyrochemical Reprocessing
- Alkaline Earth Metal Compounds
- Calcium Compounds
- Calcium Halides
- Chalcogenides
- Chemical Reactions
- Chlorides
- Chlorine Compounds
- Data
- Halides
- Halogen Compounds
- Halogenation
- Information
- Numerical Data
- Oxides
- Oxygen Compounds
- Reprocessing
- Salts
- Separation Processes
- Note
- Published through SciTech Connect.
01/01/1986.
"la-ur-86-273"
" conf-860603-4"
"DE86007387"
4. European nuclear conference and 9. FORATOM congress (ENC '86) and international nuclear trade fair, Geneva, Switzerland, 1 Jun 1986.
Simpson, J.J.; Phillips, B.J.; Davis, C.C.; McCormick, E.D.; Fife, K.W.; Bowersox, D.F. - Funding Information
- W-7405-ENG-36
View MARC record | catkey: 14666457