A Study of Oxidation of Hydrogen Based on Flashback of Hydrogen-Oxygen-Nitrogen Burner Flames
- Fine, Burton D.
- Jan. 1959.
- Physical Description:
- 1 electronic document
- Restrictions on Access:
- Unclassified, Unlimited, Publicly available. and Free-to-read Unrestricted online access
- The flashback of hydrogen-oxygen-nitrogen flames was studied as a function of pressure, burner diameter, equivalence ratio, and oxidant strength. The results were treated on the assumption that the product of the critical boundary velocity gradient for flashback and the initial concentration of that reactant which is not in excess is proportional to a mean reaction rate associated with the flame zone. It was further assumed that this reaction rate can be expressed in terms of initial concentrations and flame temperature. Measurements at constant flame temperature yield orders of reaction with respect to hydrogen and oxygen. These do not vary with flame temperature. Measurements in which pressure is varied for several values of oxidant strength at constant equivalence ratio yield a total order of reaction and a function describing the dependence of the mean reaction rate on flame temperature. The total reaction order is independent of flame temperature and equal to the sum of the orders for hydrogen and oxygen. The dependence of the reaction rate on flame temperature cannot be described by a constant activation energy. The activation energy obtained apparently increases with flame temperature. Flashback results can be described by a single rate constant which is independent of equivalence ratio. Values were estimated for this rate constant as a function of flame temperature.
- NASA Technical Reports Server (NTRS) Collection.
- Document ID: 19980228234., E-107., and NASA-MEMO-12-23-58E.
- No Copyright.
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