Direct Effects of Orbital Overlap on Reactivity -- Beyond Orbital Overlap -- Computational and Theoretical Approaches for Studies of Stereoelectronic Effects -- General Stereoelectronic Trends -- Donors, Acceptors, and Chameleons -- Stereoelectronic Effects with Donor and Acceptor Separated by a Single Bond Bridge -- Stereoelectronic Effects with Donor and Acceptor Separated by a Vinyl Bridge -- Remote Stereoelectronic Effects -- Transition State Stabilization with Stereoelectronic Effects -- Stereoelectronic Effects in Reaction Design -- Stereoelectronic Effects in Action -- Probing Stereoelectronic Effects with Spectroscopic Methods.
Summary
Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules An advanced textbook that provides an up-to-date overview of the field, starting from the fundamental principles Presents a large selection of modern examples of stereoelectronic effects in organic reactivity Shows practical applications of stereoelectronic effects in asymmetric catalysis, photochemical processes, bioorganic chemistry and biochemistry, inorganic and organometallic reactivity, supramolecular chemistry and materials science.
