- Studies in surface science and catalysis ; v. 177
- Front Cover; Morphological, Compositional, and Shape Control of Materials for Catalysis; Copyright; Contents; Contributors; Preface: Morphological, Compositional, and Shape Control of Materials for Catalysis; Chapter 1: Opportunities and Challenges in the Synthesis, Characterization, and Catalytic Properties of Controlled Nanost ...; 1.1. Introduction; 1.2. Case Studies; 1.2.1. Control of Particle Size; 1.2.2. Control of Particle Shape; 1.2.3. Control of Heterostructures; 1.3. Challenges and Opportunities, 1.3.1. Improving Synthesis and Translation to Industrial Applications of Nanostructured Catalysts1.3.2. Improving In Situ and Operando Characterization; 1.3.3. Stronger Theory-Experiment Connections; 1.3.4. Stability Issues in Nanostructured Catalysts; 1.3.5. Cost Issues Related to Well-Defined Nanostructures (Scale-Up Synthesis); 1.3.6. Toxicity Aspects of Nanostructured Catalysts; 1.4. Conclusions; References; Further reading; Chapter 2: Tuning Product Selectivity by Changing the Size of Catalytically Active Metallic Nanoparticles; 2.1. Introduction, 2.2. Tuning Product Selectivity by Changing the Size of Metallic Nanoparticles2.2.1. Influence of Platinum Particles Size on Product Selectivity in Pyrrole Hydrogenation Reaction; 2.2.2. Influence of Platinum Particles Size on Product Selectivity in 1,3-Butadiene Hydrogenation Reaction; 2.2.3. Dendrimer-Encapsulated Metallic Nanoparticles as Catalysts for Pi-Bond Activation Reactions; 2.3. Conclusions; 2.4. Perspective; 2.4.1. Formation of Subnanometer Clusters by Metal Atom Deposition on Surfaces, 2.4.2. Formation and Stabilization of Atomic Clusters by Their Encapsulation With Strongly Coordinated Surface LigandsReferences; Chapter 3: Achievements, Present Status, and Grand Challenges of Controlled Model Nanocatalysts; 3.1. Introduction; 3.2. Molecular Fundamentals of Catalysis and Controlled Nanocatalysts; 3.3. Overview of Synthetic Strategies for Controlled Nanocatalysts; 3.4. Controlled Model Nanocatalysts in Action; 3.4.1. Size and Shape Controlled Nanocatalysts; 22.214.171.124. Hydrogenation of Aromatics Over Size- and Shape-Controlled Pt NPs, and 126.96.36.199. Hydrogenative Isomerization of Methylcyclopentane Over Size- and Shape-Controlled Pt NPs188.8.131.52. Oxidation of CO Over Size-Controlled Oxyphilic Metal NPs; 3.4.2. Composition and Architecture Controlled Nanocatalysts; 184.108.40.206. Hydrogenative Reforming of Hexane Over Size and Composition Controlled Bimetallic NPs; 220.127.116.11. Preferential Oxidation of CO in H2 (PROX) Over Size and Architecture Controlled Bimetallic NPs; 3.4.3. Control of Metal-Oxide Interface; 18.104.22.168. Size-Controlled Co NPs Supported on TiO2 for Hydrogenation of CO and CO2
- 9780323446655 (electronic bk.), 0323446655 (electronic bk.), 012805090X, and 9780128050903
- Includes index.
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