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Biopolymer Grafting [electronic resource] : Synthesis and Properties

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[Place of publication not identified] : Elsevier Science Ltd, 2017.
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Contents:
Machine generated contents note: ch. 1 Synthesis and Characterization of Graft Copolymers of Plant Polysaccharides / Dilipkumar Pal -- 1.Introduction -- 2.Graft Copolymerization -- 2.1.Concept -- 2.2.Methods -- 3.Graft Copolymerization of Guar Gum -- 4.Graft Copolymerization of Gum Acacia -- 5.Graft Copolymerization of Tragacanth Gum -- 6.Graft Copolymerization of Tamarind Kernel Polysaccharide -- 7.Graft Copolymerization of Locust Bean Gum -- 8.Graft Copolymerization of Cashew Gum -- 9.Graft Copolymerization of Okra Gum -- 10.Graft Copolymerization of Fenugreek Gum -- 11.Graft Copolymerization of Gum Kondagogu -- 12.Graft Copolymerization of Gum Ghatti -- 13.Graft Copolymerization of Konjac Glucomannan -- 14.Graft Copolymerization of Psyllium Polysaccharide -- 15.Graft Copolymerization of Plant-Derived Starches -- 16.Applications of Plant Polysaccharide-g-Copolymers -- 17.Conclusion -- References -- ch. 2 Functional Separation Membranes From Grafted Biopolymers / Tadashi Uragami -- 1.Introduction -- 2.Significance for Preparation of Separation Membranes From Grafted Biopolymers -- 3.Principle of Membrane Separation Technology -- 3.1.Principle of Diffusion Dialysis -- 3.2.Principle of Reverse Osmosis -- 3.3.Principle of Nanofiltration -- 3.4.Principle of Ultrafiltration -- 3.5.Principle of Microfiltration -- 3.6.Principle of Pervaporation -- 3.7.Principle of Evapomeation -- 3.8.Principle of Gas Permeation -- 4.Technology of Grafted Biopolymer Membrane -- 4.1.Dialysis -- 4.2.Reverse Osmosis -- 4.3.Nanofiltration -- 4.4.Ultrafiltration -- 4.5.Pervaporation -- 4.6.Evapomeation -- 4.7.Gas Permeation -- 4.8.Medical, Clinical, and Other Field -- 4.9.Blood Compatibility -- 5.Conclusions -- References -- Further Reading -- ch. 3 Grafting Derivate From Alginate / Luo Wei -- 1.Introduction -- 2.Alkylated Derivatives of Alginate -- 2.1.Alkane -- 2.2.N-Octylamine -- 2.3.Oleoyl Chloride -- 3.Derivatives Based on Alginate and Acrylate and Its Derivatives -- 3.1.Acrylic Acid -- 3.2.Alkylated Acrylate -- 3.3.Other Acrylic Polymers -- 4.Derivatives Based on Alginate and Acrylamide and Its Derivatives -- 4.1.Acrylamide -- 4.2.N-Isopropylacrylamide -- 4.3.Other Derivates of Acrylamide -- 5.Derivatives Based on Alginate and Other Vinyl Monomers -- 6.Derivatives Based on Alginate and Acrylonitrile -- 7.Derivatives Based on Alginate and Various Alcohols -- 7.1.Poly(Ethylene Glycol) -- 7.2.Amphiphilic Cholesteryl -- 8.Derivatives Based on Alginate Grafted With Biomolecules -- 8.1.Cysteine -- 8.2.RGD Peptide -- 9.Derivatives Based on Alginate and Cyclodextrin -- 9.1.Amidation Reaction -- 9.2.CNBr Method -- 9.3.Self-Assembly -- 10.Derivatives Based on Alginate and Other Polymers -- References -- ch. 4 Polysaccharides in Alternative Methods for Insulin Delivery / Jaime Lizardi-Mendoza -- 1.Introduction -- 2.Proteins and Peptides as Therapeutics -- 2.1.Insulin Hormone -- 3.Insulin Administration -- 3.1.Parenteral Route -- 3.2.Sublingual Route -- 3.3.Nasal Route -- 3.4.Pulmonary Route -- 3.5.Transdermal Route -- 3.6.Oral Route -- 4.Targeted Drug Delivery -- 4.1.Colon-Specific Drug Delivery -- 5.Insulin Encapsulation Into Polymeric Reservoirs -- 5.1.Chitosan -- 5.2.Alginate -- 5.3.Dextran -- 5.4.Arabinoxylans -- 5.5.Polysaccharide Conjugates -- 5.6.Graft Copolymerization of Polysaccharides -- 6.Conclusion -- References -- ch. 5 Development of Bioactive Paper by Capsaicin Derivative Grafting Onto Cellulose / Raquel Martini -- 1.Introduction -- 1.1.Cellulose Properties -- 1.2.Cellulose Reactivity and Functionalization -- 1.3.Cellulose Application: Paper and Paperboard Packaging -- 1.4.Capsaicinoids -- 2.Capsaicin Derivative Grafting Onto Cellulose -- 2.1.Cellulose Pulp Modification: Reaction Conditions Study -- 2.2.Grafting Onto Commercial Paper: Final Properties Characterization -- 3.Conclusions -- Acknowledgments -- References -- ch. 6 Peptide-Based Derivative-Grafted Silica for Molecular Recognition System: Synthesis and Characterization / Hirotaka Ihara -- 1.Introduction -- 2.Amino Acid and Peptide -- 3.The Synthesis of Peptide and Peptide Derivatives -- 3.1.Activation -- 3.2.Protection -- 3.3.Coupling -- 4.Synthesis, Immobilization, Properties, and Applications of Peptides and Its Derivatives -- 4.1.Synthesis, Characterization, and Applications of Tripeptide-Grafted Silica [Sil-FUF (Boc-Phe-Aib-Phe-OH)] -- 4.2.Synthesis, Characterization, and Applications of Another Tripeptide-Grafted Silica [Sil-YAY (Boc-Tyrosine-Ala-Tyrosine-OH)] -- 4.3.Synthesis, Characterization, Properties, and Applications of L-Glutamic Acid-Based Peptide-Derivative-Grafted Silica (Sil-FIP and Sil-Amphi6) -- 4.4.Synthesis, Characterization, and Applications of β-Alanine-Based Peptide-Derivative-Grafted Silica (Sil-MEPG-C18-1 and Sil-MEPG-C18-2) -- 5.Synthesis, Immobilization, Properties, and Applications of Polypeptide -- 5.1.Synthesis and Properties -- 5.2.Chromatographic Evaluation of the Polypeptide Phase -- 6.Conclusion -- References -- ch. 7 Grafting Modification of Chitosan / Qu Xiaosai -- 1.Introduction -- 2.Alkylation of Chitosan -- 2.1.Reductive Alkylation of Chitosan -- 2.2.Alkylation With Alkyl Halides -- 3.Acylation of Chitosan -- 3.1.Acylation With Acyl Chloride -- 3.2.Acylation With Anhydrides -- 4.Quaternization of Chitosan -- 4.1.Quaternization of 2-NH2 of Chitosan Directly -- 4.2.Coupling the Quaternary Ammonium Groups to 2-NH2 of Chitosan -- 4.3.Quaternization of Chitosan at 6-OH -- 4.4.Quaternization of Chitosan by Grafting Copolymerization -- 5.Hydroxyalkylation of Chitosan -- 6.Carboxyalkylation of Chitosan -- 6.1.Carboxyalkylation via Schiff Base Reductive Process -- 6.2.Carboxyalkylation With Halocarboxylic Acid -- 6.3.Michael Addition -- 7.Thiolation of Chitosan -- 8.Sulfation of Chitosan -- 9.Phosphorylation of Chitosan -- 10.Graft Copolymerization of Chitosan -- 10.1.Preparation from Radical Graft Copolymerization -- 10.2.Grafting From Atom Transfer Radical Polymerization -- 10.3.Ring-Opening Graft Polymerization of Chitosan -- 10.4.Grafting Copolymerization by Using Tosyl Chitin as the Precursor -- 10.5.Coupling the Polymer Chain on the Skeleton of Chitosan -- References -- ch. 8 Nanopolymers: Graphene and Functionalization / Vijay Kumar Thakur -- 1.Introduction -- 2.Synthesis of Large-Scale Graphene by Chemical Vapor Deposition -- 2.1.Two-Step Growth Technique and Multibeam Chemical Vapor Deposition System -- 2.2.Edge Chemistry -- 3.Nucleation and Vertical Growth of Nanographene Sheets -- 4.Graphene and Graphene Oxide as Adsorbent -- 5.Adsorption Process -- 5.1.Adsorption Isotherm -- 5.2.Adsorption Kinetics -- 5.3.The Pseudo-First-Order Kinetic Model -- 5.4.The Pseudo-Second-Order Kinetic Model -- 5.5.The Intra-Particle Diffusion Kinetic Model -- 5.6.The Elovich Kinetic Model -- 6.Thermodynamic of Adsorption -- 7.Application of Graphene as Adsorbent for Removal Dyes -- 7.1.Removal of Antimony (III) by Graphene as an Adsorbent -- 7.2.Pb(II) Ion Removal by Graphene Oxide and Functionalized Graphene Oxide-Thiol -- 7.3.Removal of Cationic Dye by Graphene and Graphene Oxide as Adsorbents -- 7.4.Graphene---Fe3O4 Application for Removal Dye -- 7.5.Uranium(VI) Adsorption on Graphene Oxide Nanosheets -- 8.Applications of Graphene on Gas Sensors and Hydrogen Storage -- 8.1.Application for Ultrasensitive Carbon Oxide -- 8.2.Application Graphene in Hydrogen Storage -- 9.Applications Large-Scale Graphene by CVD Method -- 9.1.Wafer-Scale Graphene-On-Si Transistors -- 9.2.Devices -- 9.3.Synthesis of Graphene by Chemical Vapor Deposition -- 9.4.Applications of Large-Scale Graphene -- 9.5.Graphene for Nanoelectronics -- 9.6.Large-Scale Transfer of Graphene -- 9.7.CVD Graphene for Macroelectronics: Transparent Conductive Films -- 9.8.Graphene Applications in Photovoltaics -- 9.9.CVD Graphene Photovoltaic Cells on Rigid Substrates -- References -- ch. 9 Cellulose Nanocrystals Functionalization by Grafting / Silvia M. Martelli -- 1.Introduction -- 2.Extraction and Characterization of Cellulose Nanocrystals -- 3.Functionalization and Grafting in Cellulose Nanocrystals -- 4.Grafting Modifications of CNC Described in Researches -- 5.Conclusion and Outlook -- References -- ch. 10 Bioactive Materials Based on Biopolymers Grafted on Conducting Polymers: Recent Trends in Biomedical Field and Sensing / Anudeep K. Narula -- 1.Introduction -- 2.Conducting---Natural Polymers Composite: Smart Advanced Functionalized Material in Biomedical Field and Biosensing -- 2.1.Preparation Methods of Smart Functionalized Bioactive Material -- 3.Biosensing Principle of Biohybrid Polymer Composite -- 4.Biomedical Application of Biohybrid Polymer Composites -- 4.1.Tissue Engineering -- 4.2.Drug Release -- 5.Conclusion -- References -- ch. 11 Grafting of Polysaccharides: Recent Advances / Manal K. El-Bisi -- 1.Introduction -- 2.Graft of Polysaccharide Copolymers -- 2.1.Synthesis of Graft Copolymers -- 2.2.Methods of Generation of Active Sites -- 2.3.Starch Graft Copolymerization -- 2.4.Chitosan Graft Copolymerization -- 2.5.Cellulose Graft Copolymerization -- 2.6.Synthesis of Cellulose Graft Copolymers -- 2.7.Gums Graft Copolymerization -- 3.Applications of Some Polysaccharides in Different Industry -- 3.1.Introduction -- 3.2.The Pharmaceutical Application of Natural Polysaccharide -- 4.Application of Natural Polysaccharide in Textile Industry -- 4.1.Application of Starch as Warp Sizing -- 4.2.Application of Starch as Finishing -- 4.3.Application of Starch as Textile Printing -- 5.Application of Natural Polysaccharide as Flocculants -- 5.1.Nonionic Flocculants -- 5.2.Cationic Flocculants -- 5.3.Anionic Flocculants -- 6.Application of Natural Polysaccharide as Dye Removal -- 7.Application of Natural Polysaccharide as Superabsorbent -- References -- ch. 12 Grafted Nanocellulose as an Advanced Smart Biopolymer / Nurhidayatullaili M. Julkapli -- 1.Nanocellulose Biopolymer -- 1.1.Nanocellulose Biopolymer: Properties -- 2.Nanocellulose: Chemical Grafting -- and Contents note continued: 2.1.Organic Compounds Grafting -- 3.Future Applications and Perspective of Grafted Nanocellulose -- 3.1.Wastewater Treatment -- 3.2.Biomedical Applications -- 3.3.Biosensor and Bio-imaging -- 3.4.Catalysis -- 4.Conclusion.
Summary:
Biopolymer Grafting: SynthesisïÅand Properties presents the latest research and developments in fundamental of synthesis and properties of biopolymer-based graft copolymers. The book presents a broad overview of the biopolymer grafting process, along with trends in the field. It also introduces a range of grafting methods which lead to materials with enhanced properties for a range of practical applications, along with the positives and limitations of these techniques. The book bridges the knowledge gap between the scientific principles and industrial applications of polymer grafting. This book covers synthesis and characterization of graft-copolymers of plant polysaccharides, functional separation membranes from grafted biopolymers, and polysaccharides in alternative methods for insulin delivery. Recent trends and advances in this area are discussed, assisting materials scientists and researchers in mapping out the future of these new "green" materials through value addition to enhance their use.
Subject(s):
ISBN:
9780128104613 (electronic bk.)
0128104619 (electronic bk.)
9780323481045
0323481043
View MARC record | catkey: 21835242