Catalytic Routes for the Conversion of Biomass Derivatives to Hydrocarbons and/or Platform Chemicals [electronic resource].
Published
Washington, D.C. : United States. Dept. of Energy, 2015. Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy
Unprotected carbohydrates were reacted in amine-catalyzed cascade reactions with various methyl ketones to give a direct access to C-glycosides by an operationally simple protocol. As the reaction mechanism,an aldol condensation followed by an intramolecular conjugate addition is assumed.