Critical radius for nucleation [electronic resource].
Published
Oak Ridge, Tenn. : Oak Ridge National Laboratory, 1986. Oak Ridge, Tenn. : Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy
The free energy of formation and the critical radius for homogeneous nucleation of a spherical nucleus in supercooled liquid, at given temperature and ambient pressure, are determined, taking fully into account surface area, curvature, and pressure effects. The specific heats and densities of the two phases are allowed to be different and all thermophysical properties are temperature dependent. In the simple case in which classical nucleation theory is valid, the results predict a critical radius of about 40% larger than the classical value, and an activation energy barrier of almost three times larger than the classical value. 8 refs.