Polyoxometalate chemistry : from topology via self-assembly to applications / edited by Michael T. Pope and Achim Müller

Published:: New York : Kluwer Academic Publishers, [2001]
Copyright Date:: ©2001
Physical Description:: 1 online resource (vii, 427 pages) : illustrations (some color)
Additional Creators:: Pope, Michael Thor, 1933- and Müller, Achim, 1938-

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Contents:

Synthetic Strategies -- Structures: Molecular and Electronic -- Solution Equilibria and Dynamics -- From Discrete Clusters to Networks and Materials -- Applications : Catalysis, Biological Systems, Environmental Studies and Introduction to polyoxometalate chemistry : from topology via self-assembly to applications / M.T. Pope and A. Müller -- Rational approaches to polyoxometalate synthesis / R.J. Errington -- Functionalization of polyoxometalates : achievements and perspectives / A. Proust and R. Villanneau -- From the first sulfurated keggin anion to a new class of compounds based on the [M2O2S2]2 building block M=Mo, W / E. Cadot [and others] -- Organometallic oxometal clusters / A. Proust [and others] -- Spherical (icosahedral) objects in nature and deliberately constructable molecular keplerates : structural and topological aspects / O. Delgado, A. Dress, and A. Müller -- Syntheses and crystal structure studies of novel selenium- and tellurium-substituted lacunary polyoxometalates / B. Krebs, E. Droste, and M. Piepenbrink -- Vibrational spectroscopy of heteropoly acids / H. Ratajczak [and others] -- Bond-stretch isomerism in polyoxometalates? / M.-M. Rohmer [and others] -- Quantum-chemical studies of electron transfer in transition-metal substituted polyoxometalates / S.A. Borshch and H. Duclusaud -- Aqueous peroxoisopolyoxometalates / O.W. Howarth, L. Pettersson, and I. Andersson -- Molybdate speciation in systems related to the bleaching of kraft pulp / F. Taube, I. Andersson, and L. Pettersson -- NMR studies of various ligands coordinated to paramagnetic polyoxometalates / B.A. Kim and H. So -- Molecular aspect of energy transfer from Tb3+ to Eu3+ in the polyoxometalate lattices : an approach for molecular design of rare-earth metal-oxide phosphors / T. Yamase -- Conducting and magnetic organic/inorganic molecular materials based on polyoxometalates / L. Ouahab, S. Golhen, and S. Triki -- Molecular materials from polyoxometalates / J.J. Borrás-Almenar [and others] -- Framework materials composed of transition metal oxide clusters / M.I. Khan -- Perspectives in the solid state coordination chemistry of the molybdenum oxides / P.J. Hagrman, D. Hagrman, and J. Zubieta -- Polyoxometalate clusters in a supramolecular self-organized environment : steps towards functional nanodevices and thin film applications / D.G. Kurth and D. Volkmer -- Polyoxometalate chemistry : a source for unusual spin topologies / D. Gatteschi [and others] -- Heteropolyanions : molecular building blocks for ultrathin oxide films / J.D. Powell, A.A. Gewirth, and W.G. Klemperer -- Selective oxidation of hydrocarbons with hydrogen peroxide catalyzed by iron-substituted silicotungstates / N. Mizuno -- Aerobic oxidations catalyzed by polyoxometalates / A.M. Khenkin [and others] -- Polyoxoanions in catalysis : from record catalytic lifetime nanocluster catalysis to record catalytic lifetime catechol dioxygenase catalysis / R.G. Finke -- Ribosomal crystallography and heteropolytungstates / D. Janell [and others] -- Photocatalytic decontamination by polyoxometalates / A. Hiskia [and others].

Summary:

This work incorporates contributions from polyoxometalate scientists, and presents a summary of research developments in this field. Topics discussed include synthetic strategies leading to functionalized organic polyoxometalate derivatives, oxothioanions, and supramolecular assemblies.

Subject(s):

ISBN:

9780128111062 (electronic bk.)
0128111062 (electronic bk.)
0306476258
0128111054
9780128111055

Bibliography Note:

Includes bibliographical references and index.

View MARC record | catkey: 24096590