Actions for The chemical bond in inorganic chemistry : the bond valence model

Email RIS file
Bookmark
Report an Issue

The chemical bond in inorganic chemistry : the bond valence model / I. David Brown

Author
Brown, I. David (Ian David)
Published
Oxford : Oxford University Press, 2016.
Edition
Second edition.
Physical Description
1 online resource (xiii, 315 pages) : illustrations (black and white).
Access Online

Availability

I Want It
I Want It

Finding items...

Series
Contents
Machine generated contents note: 1.Historical Introduction -- 1.1.Introduction -- 1.2.Chemical Bonds -- 1.3.The Ionic Model -- 1.4.Quantum Mechanics -- 1.5.The Symmetry Model -- 1.6.Topological Models -- 1.7.Pauling's Electrostatic Valence Model -- 2.The Flux Theory of the Chemical Bond -- 2.1.Introduction -- 2.2.Theoretical Foundation -- 2.2.1.The Structure of the Atom -- 2.2.2.Electrostatic Theory -- 2.2.3.The Role of Symmetry -- 2.2.4.The Core-and-Valence-Shell Picture of the Atom -- 2.3.The Chemical Bond -- 2.3.1.The Neutral Atom Model -- 2.3.2.Coordination Numbers -- 2.3.3.Bond Networks -- 2.3.4.The Ionic Model -- 2.3.5.Some Theorems -- 2.3.6.The Covalent Model -- 2.3.7.Bond Angles -- 2.3.8.The Bond Valence Model -- 3.The Bond Valence Model -- 3.1.Introduction -- 3.2.Bond Lengths -- 3.3.Coordination Number -- 3.4.Theorems of the Bond Valence Model -- 3.4.1.Valence Sum Rule -- 3.4.2.The Distortion Theorem -- 3.4.3.Lewis Acid and Base Strength -- 3.4.4.Network Equations -- 3.4.5.Networks with Non-Bipartite Graphs -- 3.4.6.Valence Maps -- 3.4.7.Bond Angles and Valence Vectors -- 3.5.Hard and Soft Acids and Bases -- 4.Cation Coordination Number -- 4.1.Introduction -- 4.2.Anion--Anion Repulsion -- 4.3.The Bonding Strength of the Anions -- 4.4.Availability of Counterions -- 4.5.Electronic Effects -- 4.6.Steric Constraints -- 4.7.Symmetry -- 4.8.Conclusion -- 5.Hydrogen Bonds -- 5.1.Introduction -- 5.2.The Role of Anion-Anion Repulsion -- 5.3.The Normal Hydrogen Bond -- 5.4.Short Hydrogen Bonds -- 5.5.Long Hydrogen Bonds -- 5.6.The Structural Chemistry of the Hydrogen Ion -- 5.7.Other Types of Hydrogen Bond -- 5.8.Assigning Experimental Bond Valences to Hydrogen Bonds -- 6.Liquids -- 6.1.Introduction -- 6.2.Aqueous Solubility -- 6.3.Hydration of Cations -- 6.4.Protonation of Anions -- 6.5.Acidity and Alkalinity -- 6.6.Non-Aqueous Solutions and Melts -- 7.Electronically Distorted Structures -- 7.1.The Origins of Electronic Distortions -- 7.2.Modelling Electronically Distorted Structures -- 7.2.1.Multipoles -- 7.2.2.Flux Methods -- 7.2.3.Bond Valence Vectors -- 7.3.Main Group Atoms with Lone Pairs -- 7.3.1.Behaviour of Lone Pairs on Cations -- 7.3.2.Behaviour of Lone Pairs on Anions -- 7.4.Transition Metals -- 7.4.1.Early Transition Metal Cations with d0 or d1 Configurations -- 7.4.2.Jahn--Teller Distorted Cations -- 7.4.3.Late Transition Metals -- 7.5.Conclusions -- 8.Physical Properties of Bonds -- 8.1.Introduction -- 8.2.Bond Energy -- 8.3.Atomic Radii -- 8.4.Bond Lengths and Bond Angles -- 8.5.Bond Force Constants and Thermal Vibrations -- 8.6.Thermal Expansion -- 8.7.The Effects of Pressure on the Lengths of Bonds -- 8.8.The Variation of Ro with Temperature and Pressure -- 9.Space and Space Groups -- 9.1.Introduction -- 9.2.The Crystal Lattice and Translational Symmetry -- 9.3.Space Groups -- 9.4.Special Positions -- 9.5.Matching the Special Positions to the Chemistry -- 9.6.The Symmetry of Bonded Neighbours -- 9.7.Conclusion -- 10.Modelling Inorganic Structures -- 10.1.The Problem of A Priori Modelling -- 10.2.Determining the Topology -- 10.2.1.Space-Based Approaches -- 10.2.2.Chemistry-Based Approaches -- 10.2.3.Valence Maps -- 10.3.Refining the Geometry -- 10.4.Modelling Defect Structures -- 10.5.Modelling Glasses -- 10.6.Example of an A Priori Modelling: Beryl -- 10.7.Conclusion -- 11.Steric Strain -- 11.1.The Origins of Steric Strain -- 11.2.Measurement of Steric Strain -- 11.3.Relaxation of Steric Strain -- 11.3.1.Relaxation of the Geometry -- 11.3.2.Relaxation by Defects -- 11.3.3.Electronic Relaxation -- 11.3.4.Effects of Temperature and Displacive Phase Transitions -- 11.3.5.Changing the Bond Graph---Reconstructive Phase Transitions -- 11.3.6.Summary of Relaxations -- 11.4.Incommensurate Structures -- 12.Applications -- 12.1.Introduction -- 12.2.Crystallography -- 12.2.1.Structure Determination -- 12.2.2.Analysis of Crystal Structures -- 12.3.Physics -- 12.3.1.Perovskite-Related Solids -- 12.3.2.Electrical Properties -- 12.3.3.Magnetic Properties -- 12.3.4.Other Physical Properties -- 12.4.Chemistry -- 12.4.1.Non-Diffraction Techniques -- 12.4.2.Heterogeneous Catalysis -- 12.4.3.Esterification and Hydrolysis -- 12.4.4.Education -- 12.5.Mineralogy -- 12.5.1.Soil Chemistry -- 12.5.2.Zeolites -- 12.5.3.Glasses -- 12.6.Materials -- 12.6.1.Crystal Growth -- 12.6.2.Surfaces and Interfaces -- 12.7.Biology -- 12.7.1.Enzymes -- 12.7.2.Calcium and Sodium Binding by Proteins -- 12.8.Databases -- 13.Chemical Implications of the Bond Valence Model -- 13.1.Historical Development of the Bond Theory -- 13.2.The Complementary Natures of the Flux and Quantum Theories -- 13.3.Properties of the Bond Flux -- 13.4.Relationship to Other Chemical Models -- 13.5.Conclusion -- Appendix 1 Determining Bond Valence Parameters -- A1.1.Introduction -- A1.2.Determination of Bond Valence Parameters -- A1.2.1.Methods of Determining Bond Valences -- A1.2.2.Selection of the Target Set of Observed Atomic Environments -- A1.2.3.Refinement -- A1.2.4.Special Cases -- A1.3.Other Expressions -- Appendix 2 Space Group Spectra -- Appendix 3 Refcodes for Crystal Structures -- Appendix 4 Glossary.
Summary
This text describes the bond valence model, a description of acid-base bonding which is becoming increasingly popular particularly in fields such as materials science and mineralogy where solid state inorganic chemistry is important.
Subject(s)
ISBN
9780191802935 (ebook)
Audience Notes
Specialized.
Note
This edition previously issued in print: 2016.
Bibliography Note
Includes bibliographical references and index.
View MARC record | catkey: 28938134