A mass-spectrometric effusion study of the vaporization of uranium monophosphide has been completed. Between 2073 and 2423 deg K, the monophosphide does not vaporize congruently, but instead loses phosphorus preferentially, forming a two-phase system. The vapor species observed were U(g), P(g), and P2(g). The temperature dependencies of the partial pressures in atmospheres are given. A value for the enthalpy of sublimation of uranium at 298 deg K was found to be 129.0 +- 3.7 kcal/mole from averaging our second- and third-law values, which were in good agreement with each other.
U.S. Atomic Energy Commission depository collection.
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DOE contract number: W-31-109-ENG-38 NSA number: NSA-23-024137 OSTI Identifier 4798834 Research organization: Argonne National Lab., IL (United States).