ELECTROCHEMISTRY, THERMOCHEMISTRY AND FUSED SALTS. Annual Progress Report, January 1, 1963-December 31, 1963

Author: Jordan, J.
Published: United States : [publisher not identified], 1964.
[Oak Ridge, Tennessee] : [U.S. Atomic Energy Commission], 1964.
Physical Description: microfiche : negative ; 8 x 13 cm

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Summary

BS>Electron transfer and acid-base chemistry in molten nitrate and chloride environments is being studied. The foundation of a Lux-Flood base- strength scale'' was laid, based on oxide donor-acceptor properties in fused salts. Polarography and thermometric titrations were used cooperatively to clarify the endothermic oxidation of Cr(III) to Cr(IV) in a chloride solvent at 400 deg C. Model studies in aqueous solutions were carried out on the thermochemistry of inert ion pair complexes and on the electrochemistry of a divalent thallium species. An advanced version of the Kelly-- Fisher controlled- potential polarograph was constructed. Two single-crystal silver electrodes were prepared. (M.C.G.)

Report Numbers

TID-20114

Other Subject(s)

Collection

U.S. Atomic Energy Commission depository collection.

Note

DOE contract number: AT(30-1)-2133
NSA number: NSA-18-012042
OSTI Identifier 4117023
Research organization: Pennsylvania State Univ., University Park. Coll. of Chemistry and Physics.

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