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Advances in organometallic chemistry. Volume sixty two / edited by Pedro J. Pérez ; founding editors, F. Gordon A. Stone, Robert West ; contributors, Mathieu Achard [and eleven others].

Published
London, England : Academic Press, 2014.
Copyright Date
©2014
Edition
First edition.
Physical Description
1 online resource (316 pages) : illustrations, tables
Additional Creators
Perez, Pedro J., 1965-, Stone, F. Gordon A., West, Robert, 1928-, and Achard, Mathieu
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Contents
Front Cover; Advances in Organometallic Chemistry; Copyright; Contents; Contributors; Chapter One: Palladium-Mediated Organofluorine Chemistry; 1. Introduction; 2. CC Coupling Reactions of Fluorinated Reagents; 2.1. Overview of catalytic CC coupling reactions of fluorinated derivatives; 2.1.1. CC coupling of fluorinated alkyl derivatives; 2.1.1.1. Radical reactions; 2.1.1.2. Perfluoroalkyl groups in the Stille reaction; 2.1.1.3. Introduction of fluorinated groups using the Negishi reaction; 2.1.1.4. Introduction of fluorinated groups using the Suzuki reaction., 2.1.1.5. Use of fluoroalkyl silanes as fluoroalkylating reagents2.1.1.6. Other fluoroalkylating reagents: Fluoroalkyl copper; 2.1.1.7. Allylic alkylation reactions; 2.1.1.8. Catalysis through palladium mediated CH activation; 2.1.1.9. Perfluoroalkylation of unsaturated molecules; 2.1.2. CC coupling of fluorinated aryl derivatives; 2.1.2.1. Heck reactions; 2.1.2.2. Suzuki-Miyaura reactions; 2.1.2.3. Stille reactions; 2.1.2.4. Sonogashira reactions; 2.1.3. CC coupling of fluorinated arenes; 2.1.4. CC coupling of fluorinated alkenyls; 2.2. The PdRF bond; 2.2.1. PdAlkylF bonds; 2.2.2. PdArF bonds., 2.3. Elementary steps in organofluorine CC coupling palladium-catalyzed processes2.3.1. Oxidative addition and related processes; 2.3.1.1. Oxidative addition to Pd(0) compounds; 2.3.1.2. Oxidation of Pd(II) compounds leading to organofluorine Pd(IV) derivatives; 2.3.2. Transmetalation; 2.3.2.1. The transmetalation step in the Stille reaction; 2.3.2.2. Transmetalation equilibria between organogold and organopalladium complexes; 2.3.2.3. The transmetalation step in the Negishi reaction; 2.3.3. Reductive elimination; 2.3.3.1. Reductive elimination from Pd(II) complexes., 2.3.3.2. Reductive elimination from Pd(IV) complexes2.3.4. 2,1-Insertion; 2.3.5. 1,1-Insertion (migratory insertion); 3. CF Activation and Fluorination; 3.1. Overview of catalytic CC and CX coupling reactions where a CF bond is cleaved; 3.1.1. CC coupling reactions of fluorinated aryls; 3.1.2. CC Coupling reactions of fluorinated alkenes; 3.1.3. Allylic substitutions of a fluorine atom; 3.1.4. Hydrodefluorination reactions; 3.2. Overview of catalytic CF forming reactions; 3.2.1. Pd-catalyzed fluorination with electrophilic fluorine sources., and 3.2.2. Pd-catalyzed fluorination with nucleophilic fluorine sources3.3. The PdF bond; 3.4. Oxidative addition of RF; 3.5. β-F and α-F elimination; 3.6. Other activation routes for CF cleavage; 3.7. Reductive elimination of RF; 4. Conclusion; Acknowledgment; References; Chapter Two: Normal and Abnormal N-Heterocyclic Carbene Ligands: Similarities and Differences of Mesoionic C-Donor Complexes; 1. Introduction and General Considerations; 2. Ligand Nomenclature: Abnormal or Mesoionic Carbene Complexes?; 3. Electronic Considerations; 4. Reactivity of Complexes with Sterically Comparable Ligands.
Summary
This book contains authoritative reviews regarding the field of Organometallic Chemistry, written by highly qualified experts within the area, and reviewed by other experts before publication. Because of this high standard, AOC is one of the most cited journals in both Organic and Inorganic Chemistry fields.
Subject(s)
ISBN
9780128010846 (electronic bk.)
0128010843 (electronic bk.)
9780128009765
Bibliography Note
Includes bibliographical references at the end of each chapters and index.
View MARC record | catkey: 45341265