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Unusual bond paths in organolithium compounds

Author
Bachrach, S. M.
Published
United States : [publisher not identified], 1986
Springfield, Va.: National Technical Information Service, [approximately 1986]
Physical Description
microfiche : negative ; 11 x 15 cm
Additional Creators
Ritchie, J. P.

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Summary
We have applied the topological method to a number of organolithium compounds. The wavefunctions were determined with GAUSSIAN-82 using 3-21G basis set and fully optimized geometries. Gradient paths were obtained using the RHODER package and critical points were located using EXTREME. These results indicate the unusual nature of organolithium compounds. The strange bond paths arise mainly from the ionic nature of the C-Li interaction. We suggest that the term ''bond path'' may best be suited for covalent bonds. 4 figs., 1 tab.
Report Numbers
DE86012441; LA-UR-86-2181; CONF-8606165-1
Other Subject(s)
Collection
NTIS collection.
Note
DOE contract number: W-7405-ENG-36
OSTI Identifier 5391131
Research organization: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States).
View MARC record | catkey: 47365813