Actions for Carbon-based solids and materials
Carbon-based solids and materials / Pierre Delhaes
- Author
- Delhaes, Pierre
- Published
- London, UK : ISTE ; Hoboken, NJ : Wiley, 2011.
- Physical Description
- xvi, 640 pages : illustrations ; 25 cm
- Contents
- Machine generated contents note: pt. 1 Carbon Phases, Precursors and Parent Compounds -- ch. 1 A Historical Overview -- 1.1.The alchemy of carbon -- 1.2.Elemental carbon and its allotropic varieties -- 1.3.Novel molecular varieties -- 1.4.Natural forms -- 1.4.1.Carbon: witness of the evolution of the universe -- 1.4.2.Natural carbons from Earth -- 1.4.3.Comparison between natural and artificial carbons -- 1.5.Contribution from quantum mechanics -- 1.5.1.Homonuclear diatomic molecules -- 1.5.2.Curved surfaces: the rehybridization phenomena -- 1.5.3.Presentation of the crystalline forms -- 1.5.4.The isotopes of the carbon atom -- 1.6.Conclusion -- 1.7.Bibliography -- ch. 2 Polymorphism of Crystalline Phases -- 2.1.Thermodynamic stability and phase diagram -- 2.1.1.Stable and metastable phases -- 2.1.2.The phase diagram of carbon -- 2.1.3.Case of the molecular phases -- 2.1.4.Crystallographic presentation of usual phases -- 2.2.Classical forms of carbon -- 2.2.1.Cohesive energy and equation of state for solids -- 2.2.2.Structures with a fixed coordination number -- 2.3.Molecular and exotic forms -- 2.3.1.Tri-coordinated structures on curved surfaces -- 2.3.2.Exotic structures with mixed coordination numbers -- 2.4.State of the art and conclusion -- 2.5.Bibliography -- ch. 3 Non-Crystalline Carbons -- 3.1.Reminder about defects and imperfections in networks -- 3.1.1.Ideal single crystals -- 3.1.2.Crystalline imperfections -- 3.1.3.Non-crystalline solids -- 3.1.4.Homogenity of a solid -- 3.2.Thermodynamic approach and the classification of solids -- 3.2.1.Generalities -- 3.2.2.Classification of carbon-based materials -- 3.3.Fabrication and characterization techniques -- 3.3.1.Thin-film coating techniques -- 3.3.2.Deposition mechanisms -- 3.3.3.The role of catalysts -- 3.3.4.Characterizations at different scales -- 3.4.Conclusion -- 3.5.Bibliography -- ch. 4 Derivative Compounds and Analogs -- 4.1.Doping carbons and solid solutions -- 4.1.1.Doped diamonds -- 4.1.2.Doped graphitic phases -- 4.1.3.Fullerenes and nanotubes doping -- 4.2.2D and 3D analog compounds -- 4.2.1.Boron nitride -- 4.2.2.Boron carbides -- 4.2.3.Carbon nitrides -- 4.2.4.Carbon-boron nitrides -- 4.3.Similar materials -- 4.3.1.Aggregates and inorganic nanotubes -- 4.3.2.Bulk compounds -- 4.4.Conclusion -- 4.5.Bibliography -- ch. 5 From Aromatic Precursors to the Graphene Plane -- 5.1.Condensed polyaromatic systems -- 5.1.1.Presentation of condensed aromatic molecules -- 5.1.2.Thermochemical evolution of organic precursors -- 5.1.3.Association of aromatic molecules and supramolecular organization -- 5.1.4.Structural and physico-chemical characteristics of low temperature carbons -- 5.2.The graphene plane -- 5.2.1.Characteristics and properties -- 5.2.2.Growth in the vapor phase and thermodynamic stability -- 5.2.3.Intercalation and exfoliation processes -- 5.3.Current situation and conclusion -- 5.4.Bibliography -- pt. 2 Physical Properties of Solid Carbons -- ch. 6 General Structural Properties -- 6.1.Elastic and mechanic properties -- 6.1.1.Reminder of the main definitions -- 6.1.2.Elasticity modulus of crystalline phases -- 6.1.3.Behavior laws relative to bulk polycrystalline graphites -- 6.1.4.Behavior laws for carbon filaments -- 6.2.Thermal properties -- 6.2.1.Thermodynamic definitions -- 6.2.2.Specific heat -- 6.2.3.Thermal dilatation -- 6.2.4.Thermal conductivity -- 6.3.Conclusion -- 6.4.Bibliography -- ch. 7 Electronic Structures and Magnetic Properties -- 7.1.Electronic band structures -- 7.1.1.Band structure of hexagonal graphite single crystals -- 7.1.2.Experimental evaluations of energy parameters -- 7.1.3.Models for graphitic carbons -- 7.1.4.Electronic dimensionality of π solids -- 7.2.Static magnetic properties -- 7.2.1.General presentation of diamagnetism -- 7.2.2.Graphite single crystal and graphene plane -- 7.2.3.Different varieties of graphitic carbons -- 7.2.4.Quantum phenomena on carbon nanotubes -- 7.3.Electron spin (or paramagnetic) resonance -- 7.3.1.General characteristics of ESR/EPR -- 7.3.2.The Pauli paramagnetism of graphites -- 7.3.3.EPR of various carbon varieties -- 7.3.4.Magnetic interactions -- 7.4.NMR -- 7.4.1.Non-crystalline carbons and precursors -- 7.4.2.Case of graphite and related compounds -- 7.5.Conclusion -- 7.6.Bibliography -- ch. 8 Electronic Transport Properties -- 8.1.Electrical conductivity -- 8.1.1.Different conduction mechanisms -- 8.1.2.Transport in the ballistic regime -- 8.1.3.Non-ohmic transport and applications -- 8.1.4.Electromechanical properties -- 8.2.Galvanomagnetic properties -- 8.2.1.Evolution of graphitic carbons in classical regime -- 8.2.2.Quantum phenomena in crystalline phases -- 8.2.3.Comparison between different types of graphitic compounds -- 8.3.Thermoelectric properties -- 8.3.1.Graphites and bulk carbons -- 8.3.2.Carbon filaments -- 8.3.3.Thermomagnetic effects -- 8.3.4.Remark on electronic thermal conductivity -- 8.4.Conclusion -- 8.5.Bibliography -- ch. 9 Optical Properties and their Applications -- 9.1.Properties in linear optics -- 9.1.1.Experimental techniques and general presentation -- 9.1.2.Single crystal of graphite -- 9.1.3.Graphitic carbons -- 9.1.4.Fullerenes and nanotubes -- 9.1.5.The diamond crystals -- 9.1.6.Adamantine carbons -- 9.2.Nonlinear and photo-induced properties -- 9.2.1.Luminescence in diamond-type phases -- 9.2.2.Photo-induced and nonlinear effects in fullerenes -- 9.2.3.Photo-induced and nonlinear effects in nanotubes -- 9.3.Analysis methods and applications -- 9.3.1.Overview of the relevant techniques -- 9.3.2.Applications in optics and optoelectronics -- 9.4.Conclusion -- 9.5.Bibliography -- ch. 10 Vibrational Properties -- 10.1.Phonon spectra in crystalline phases -- 10.1.1.Diamonds -- 10.1.2.Graphite and graphene -- 10.1.3.Nanotubes -- 10.1.4.Carbynes and fullerenes -- 10.1.5.Comparison between elongation modes -- 10.2.Specific characteristics of Raman scattering -- 10.2.1.Raman resonance of graphite -- 10.2.2.Raman resonance of π systems and electron-phonon interactions -- 10.2.3.Influence of structural disorder -- 10.2.4.Characterization of non-crystalline carbons -- 10.3.Data from infrared spectroscopy -- 10.3.1.Thermochemical evolution of carbon-based precursors -- 10.3.2.Analysis of surface functions -- 10.4.Conclusion -- 10.5.Bibliography -- pt. 3 Carbon Materials and Uses -- ch. 11 Surface and Interface Phenomena -- 11.1.Physical-chemistry characteristics -- 11.1.1.Surface properties in diamonds and graphites -- 11.1.2.Case of graphitic-type phases -- 11.1.3.Adsorption mechanisms -- 11.2.Electric and electrochemical aspects -- 11.2.1.Double layer model and electrokinetic potential -- 11.2.2.Electronic transfers -- 11.3.Solid interfaces, tribology and mechano-chemical effects -- 11.3.1.Interactions between solid surfaces in motion -- 11.3.2.Grinding of graphitic powder -- 11.3.3.Friction coefficients of diamond phases -- 11.3.4.Friction coefficients of graphitic phases -- 11.3.5.Wear and lubrication -- 11.4.Conclusion -- 11.5.Bibliography -- ch. 12 Chemical Reactivity and Surface Treatment -- 12.1.Oxidation reactions -- 12.1.1.Review of the reactions with molecular oxygen -- 12.1.2.Combustion mechanism of various carbons -- 12.1.3.Selectivity between different phases -- 12.1.4.Other gaseous oxidants -- 12.1.5.Oxidation in the liquid phase -- 12.1.6.Oxidations in the solid phase -- 12.1.7.Technical analysis relevant to surface functions -- 12.2.Hydrogenation and halogenation reactions -- 12.2.1.Reactions with hydrogen -- 12.2.2.Reactions with halogens -- 12.3.Surface treatment and heterogenous catalysis -- 12.3.1.Surface modifications -- 12.3.2.Catalytic effects -- 12.4.Conclusion -- 12.5.Bibliography -- ch. 13 Divided and Porous Carbons -- 13.1.General presentation of heterogenous carbons -- 13.1.1.Basic classification -- 13.1.2.Carbons from a solid phase -- 13.1.3.Carbons from a liquid phase -- 13.1.4.Porous carbons with a gas phase -- 13.2.Properties of porous carbons -- 13.2.1.Porous textures and surface characteristics -- 13.2.2.Dynamic properties -- 13.3.Competition between chemical reactions and diffusion -- 13.3.1.The Thiele model and its ramifications -- 13.3.2.Chemical deposition in the vapor phase -- 13.3.3.Formation from energetic processes -- 13.4.Conclusion -- 13.5.Bibliography -- ch. 14 Carbon Filaments, Composites and Heterogenous Media -- 14.1.Carbon filaments -- 14.1.1.History of nanofilaments -- 14.1.2.Evolution of carbon fibers -- 14.1.3.Main physical characteristics of carbon filaments -- 14.2.Role in composite materials -- 14.2.1.Multidimensional and multiscale systems -- 14.2.2.Fiber-matrix interactions -- 14.2.3.Classes of composites and nanocomposites -- 14.3.Random heterogenous media -- 14.3.1.Electrical conductivity and percolation models -- 14.3.2.Role of interfacial properties and influence of the matrix -- 14.3.3.Consequences of the percolation phenomenon -- 14.4.Conclusion -- 14.5.Bibliography -- ch. 15 Use of Carbon Materials -- 15.1.Sensing applications and nanoelectronics -- 15.1.1.Sensors and actuators -- 15.1.2.Nanoelectronic -- 15.2.Carbon for energy -- 15.2.1.Solar radiations, conversion, and heat storage -- 15.2.2.Gas storage -- 15.2.3.Electrochemical storage -- 15.2.4.Carbons in nuclear energy -- 15.3.Thermostructural composites and transport -- 15.3.1.Space applications -- 15.3.2.Braking disks -- 15.4.Carbons for chemistry and environmental problems -- 15.4.1.Applications in industrial chemistry -- 15.4.2.Carbon and environment -- 15.5.Biocarbons -- 15.5.1.Prosthesis and medical implants -- 15.5.2.Biological fluids and hemocompatibility -- 15.5.3.Nanotoxicology -- 15.5.4.Application trends -- 15.6.General conclusion -- 15.7.Bibliography.
- Subject(s)
- ISBN
- 9781848212008
1848212003 - Note
- "Adapted and updated from three volumes Solides et matériaux carbonés 1, 2, 3 published 2009 in France by Hermes Science/Lavoisier ... 2009"--T.p. verso.
- Bibliography Note
- Includes bibliographical references and index.
- Source of Acquisition
- Engineering copy: Purchased with funds from the J. Harvey Fahnestock Endowment for Scientific, Engineering and Rare Books; 2010.
- Endowment Note
- J. Harvey Fahnestock Endowment for Scientific, Engineering and Rare Books
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