The power of click chemistry for molecular machines and surface patterning [electronic resource] / Jason M. Spruell
- Author:
- Spruell, Jason M.
- Published:
- New York : Springer, [2011]
- Copyright Date:
- ©2011
- Physical Description:
- 1 online resource (xvii, 119 pages)
Access Online
- SpringerLink: ezaccess.libraries.psu.edu
- Series:
- Contents:
- Machine generated contents note: 1.Kinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds -- 1.1.Introduction -- 1.2.Highly Efficient Kinetically Controlled Syntheses of [2]Rotaxanes -- 1.3.Syntheses of [n]Catenanes Under Kinetic and Thermodynamic Control -- 1.4.Formation of Higher Order Rotaxanes Using CuAAC -- 1.5.Shuttling and Switching Within Triazole-Containing [2]Rotaxanes -- 1.6.Incorporating Mechanical Bonds into Materials and New Environments -- 1.7.Conclusions -- References -- 2.Efficient Templated Synthesis of Donor-Acceptor Rotaxanes Using Click Chemistry -- 2.1.Introduction -- 2.2.Results and Discussion -- 2.3.Conclusions -- 2.4.Experimental Section -- 2.4.1.General Methods -- References -- 3.A One-Pot Synthesis of Constitutionally Unsymmetrical Rotaxanes Using Sequential Cu(I)-Catalyzed Azide-Alkyne Cycloadditions -- 3.1.Introduction -- 3.2.Results and Discussion -- 3.3.Conclusions -- 3.4.Experimental -- 3.4.1.General Methods -- References -- 4.Heterogeneous Catalysis Through Microcontact Printing -- 4.1.Introduction -- 4.2.Results and Discussion -- 4.3.Conclusions -- 4.4.Experimental Section -- 4.4.1.Reagents and General Methods -- 4.4.2.Synthesis of Ferrocene Alkyne (5) -- 4.4.3.Synthesis of Pentafluorophenylether Alkyne (6) -- 4.4.4.Gold Substrates -- 4.4.5.Formation of Mixed Azide Terminated SAMs on Gold -- 4.4.6.PDMS Stamp Preparation [14] -- 4.4.7.Metal-Coated PDMS Stamp Preparation -- 4.4.8.StampCat on Gold -- 4.4.9.StampCat on Glass -- 4.4.10.Reagent-Stamping on Gold -- 4.4.11.Solution-Surface Functionalization on Gold -- 4.4.12.Solution Reaction of 1 -Azidohexane (3) and 1-Octyne (4) -- 4.4.13.Electrochemical Measurements -- 4.4.14.X-Ray Photoelectron Spectroscopy -- 4.4.15.Contact Angle Measurements -- 4.4.16.Infrared Surface Characterization -- 4.4.17.Atomic Force Microscopy (AFM) Imaging -- 4.4.18.Laser Scanning Confocal Microscopy/Optical Microscopy -- References -- 5.Heterogeneous Catalysis of a Copper-Coated Atomic Force Microscopy Tip for Direct-Write Click Chemistry -- 5.1.Introduction -- 5.2.Results and Discussion -- 5.3.Conclusions -- 5.4.Experimental Section -- 5.4.1.Microcontact Printing of Alkyne Molecules onto Azide-Terminated Silicon Wafer Pieces -- 5.4.2.Direct-Write Click Chemistry of Propargyl-Amine and TEG-Alkyne -- 5.4.3.Control Experiments -- 5.4.4.Materials -- 5.4.5.AFM -- References -- 6.A Push-Button Molecular Switch -- 6.1.Introduction -- 6.2.Results and Discussion -- 6.3.Conclusions -- 6.4.Experimental Section -- 6.4.1.General Methods -- 6.4.2.Computational Methods -- 6.4.3.Preparation of 3 -- 6.4.4.Preparation of 4 -- 6.4.5.Preparation of 1.4PF6 -- References -- 7.Highly Stable TTF Radical Dimers in a Five-State [3]Catenane -- 7.1.Introduction -- 7.2.Results and Discussion -- 7.3.Conclusions -- 7.4.Experimental Section -- 7.4.1.General Methods -- 7.4.2.Computational Methods -- 7.4.3.Preparation of 1.4PF6 -- 7.4.4.Oxidation Studies -- References.
- Subject(s):
- ISBN:
- 9781441996473 (electronic bk.)
1441996478 (electronic bk.) - Dissertation Note:
- Ph. D. Northwestern University.
- Note:
- AVAILABLE ONLINE TO AUTHORIZED PSU USERS.
- Bibliography Note:
- Includes bibliographical references and index.
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